KOBAYASHI Nagao

Faculty of Textile Science and Technology 

Professor 

Researcher Information

Degree

  • Doctor of Pharmacy, Tohoku University(Japan)
  • Doctor of Science, Tohoku University(Japan)

Field Of Study

  • Structural organic chemistry and physical organic chemistry, Physical organic chemistry

TEL

    +81-268-21-5499

Mail Address

    nagaok★shinshu-u.ac.jp

Educational Background

  • 1978, Tohoku University, Guraduate School of Science, Chemistry
Research activity information

Paper

  • Preparation, Optical and Electrochemical Properties, and Molecular Orbital Calculations of Tetraaza- porphyrinato Ruthenium (II) Bis(4-methylpyridine) Fused with One to Four Diphenylthiophene Units.
    T. Kimura, N. Murakami, E. Suzuki, T. Furuyama, T. Nakahodo, H. Fujihara, N. Kobayashi
    J. Inorgbio. Chem., 158, 35-44, 2016
  • Pyrene-Bridged Subphthalocyanine Dimers: Combination of Planar and Bowl-Shaped -Conjugated Systems for Creating Uniquely Curved -Conjugated Systems.
    S. Nakano, Y. Kage, H. Furuta, N. Kobayashi, S. Shimizu
    Chem. Eur. J., 22, 7706-7710, 2016
  • Topological Control of Columnar Stacking Made of Liquid Crystalline Thiophene-Fused Metallonaphthalocyanines.
    H. Suzuki, K. Kawano, K. Ohta, Y. Shimizu, N. Kobayashi, and M. Kimura
    ChemistryOpen., 5, 150 – 156, 2016
  • Synthesis, Optical Property, and Electronic Structures of Tetrakis(pentafluorophenyl)tetrathiaisophrorin Dioxide.
    V. J. Mishra, T. Furuyama, N. Kobayashi, K. Goto, T. Miyazaki, J. –S. Yang, and T. Shinmyozu
    Chem. Eur. J., 22, 9190-9197, 2016
  • Contorted Arens-fused Metallophthjalocyanines.
    H. Suzuki, N. Kobayashi, M. Kimura
    5, 506-512, 2016
  • Low-Symmetrical Zinc(II) Benzonaphthoporphyrazine Sensitizers for Light-Harvesting in Near-IR Region of Dye-Sensitized Solar Cells
    T. Ikeuchi, N. Kobayashi, M. Kimura
    Inorg. Chem., 55, 5014-5018, 2016
  • Sandwich-type Bis(tetradiazepinoporphyrazinato) Rare Earth Complexes: Crucial Role of Intermolecular Hydrogen Bonding.
    E. N. Tarakanova, S. A. Trashin, A. O. Shimakov, T. Furuyama, A. V. Dzuban, L. N. Inasaridze, P. A. Tarakanov, P. A. Troshin, V. E. Pushkarev, N. Kobayashi, L. G. Tomilova
    Dalton Trans., 45, 12041–12052, 2016
  • Template Synthesis of Decaphyrin without Meso-Bridges: Cyclo[10]pyrrole.
    T. Okujima, C. Ando, S. Agrawal, H. Matsumoto, S. Mori, K. Ohara, I. Hisaki, T. Nakae, M. Takase, H. Uno, N. Kobayashi
    J. Am. Chem. Soc., 138, 7540-7543, 2016
  • Formation of a Trithia[5]helicene in an Unexpected Photoreaction of a Methyl-Substituted Bis(dithienylethenyl)thiophene through a Double Sequence of 6-Electrocyclization–Aromatization (Dehydrogenation/ Demethylation)
    A. Yamamoto, Y. Matsui, E. Ohta, T. Ogaki, H. Sato, T. Furuyama, N. Kobayashi, K. Mizuno, H. Ikeda
    J. Photochem. Photobiol. A: Chemistry, 331, 48-55, 2016
  • A Novel Isoindole-Containing Polyaromatic Hydrocarbon Unexpectedly Formed during the Synthesis of meso-2,6-Dichlorophenyl-Substituted Tribenzosubporphyrin.
    Y. Shiina, H. Karasaki, S. Mori, N. Kobayashi, H. Furuta, S. Shimizu
    J. Porphyrins Phthalocyanines, 20, 1049-1054, 2016
  • Synthesis, Characterization and Electronic Structures of Porphyrins Fused with Polycyclic Aromatic Ring Systems.
    T. Okujima, J. Mack, J. Nakamura, T. Nyokong, H. Zhu, N. Komobuchi, N. Ono, H. Yamada, H. Uno, N. Kobayashi
    Chem. Eur. J., 22, 14730-14738, 2016
  • Simple Primary b-Amino Alcohol Catalyzed Enantioselective Diels-Alder Reaction of 3-Hydroxy-2- pyridones
    T. Takahashi, S. Reddy, Y. Kohari, C. Seki, T. Furuyama, N. Kobayashi, Y. Okuyama, E. Kwon, K. Uwai, M. Tokiwa, M. Takeshita, H. Nakano
    Tet. Lett., 57, 5771-5776, 2016
  • Low-Symmetrical Omega-shaped Zinc Phthalocyanine Sensitizers Having a Panchromatic Light Harvesting Property for Dye-sensitized Solar Cells.
    S. Yamamoto, S. Mori, A. Zhang, M. J. Stillman, N. Kobayashi, M. Kimura
    Chem. Eur. J., 22, 18760-18768, 2016
  • Synthesis of meta-Methoxyphenyl Substituted Tetraazaporphyrin and Corrolazine Phosphorus(V) Complexes.
    T. Furuyama, Y. Sugiya, T. Yoshida, N. Kobayashi
    J. Porphyrins and Phthalocyanines, 20, 1075-1081, 2016
  • Aggregation Control of Robust Water-Soluble Zinc(II) Phthalocyanine-based Photosensitizers.
    T. Ikeuchi, J. Mack, T. Nyokong, N. Kobayashi, M. Kimura
    LANGMUIR, 32, 11980-11985, 2016
  • Rational Molecular Design towards Vis/NIR Absorption and Fluorescence by Using Pyrrolopyrrole aza-BODIPY and Its Highly-Conjugated Structures for Organic Photovoltaics
    S. Shimizu, T. Iino, A. Saeki, S. Seki, N. Kobayashi
    Chem. Eur. J., 21, 2893-2904, 2015
  • Asymmetric Core-Expanded Aza-BODIPY Analogues: Facile Synthesis and Optical Properties.
    H. Liu, H. Lu, Z. Zhou, S. Shimizu, Z. Li, N. Kobayashi, Z. Shen
    Chem. Commun., 51, 1713-1716, 2015
  • Synthesis, Spectral Properties and TD-DFT Calculations of Nonclassical Binuclear Thienoporphyrazines.
    T. V. Dubinina, N. E. Borisova, L. G. Tomilova, T. Furuyama, N. Kobayashi
    Dyes & Pigm., 117, 1-6, 2015
  • Dinitriles Having AIE-Active Moieties: Synthesis, E/Z Isomerization and Fluorescence Properties.
    T. T. Tasso, T. Furuyama, N. Kobayashi
    Chem. Eur. J., 21, 4817-4824, 2015
  • Optical, Electrochemical, and Magnetic Properties of Pyrrole- and Thiophene-Bridged 5,15-Diazaporphyrin Dimers.
    S. Omomo, H. Maruyama, K. Furukawa, T. Furuyama, H. Nakano, N. Kobayashi, Y. Matano
    Chem. Eur. J., 21, 2003-2010, 2015
  • One-Step Reaction that Yields Highly Twisted and Fully π-Conjugated Porphyrinic Oligomers.
    S. Ito, S. Hiroto, S. Lee, M. Son, I. Hisaki, T. Yoshida, D. Kim, N. Kobayashi, H. Shinokubo
    J. Am. Chem. Soc., 137, 142-145, 2015
  • Synthesis and Optical Properties of Tetraazaporphyrin Phosphorus(V) Complexes Substituted with Electron-Rich Heteroatoms.
    T. Yoshida, T. Furuyama, N. Kobayashi
    Tet. Lett., 56, 1671-1674, 2015
  • Metallophthalocyanin-ocenes: Scandium Phthalocyanines with An η5-Bound Cp Ring.
    R. H. Platerl, T. T. Tasso, W. Zhou, T. Furuyama, N. Kobayashi, D. B. Leznoff
    Chem. Commun., 51, 5986-5989, 2015
  • Cyclophanes Containing Bowl-Shaped Aromatic Chromophores: Three Isomers of anti-[2.2](1,4)Subphthalocyaninophane
    Q. Liu, S. Shimizu, N. Kobayashi
    Angew. Chem. Int. Ed., 54, 5187-5191, 2015
  • Structural Changes in Non-planar Octaaryl Substituted Phthalocyanine Phosphorus Complexes.
    T. Furuyama, R. Harako, N. Kobayashi
    J. Porphyrins and Phthalocyanines,, 19, 500-509, 2015
  • Facile Synthesis, Spectroscopic and Electrochemical Properties, and Theoretical Calculations of Porphyrin Dimers with a Bridging Amide-bonded Xanthene Moiety.
    X. Liang, L. Xi, J. Mack, J. Stone, T. Nyokong, Y. Jiang, N. Kobayashi, W. Zhu
    J. Porphyrins and Phthalocyanines, 19, 819-829, 2015
  • Fluorescence Enhancement of Tetraazaporphyrins by the Use of Bulky Substituent Effects.
    T. Yoshida, T. Furuyama, M. Asai, and N. Kobayashi
    Chem. Lett., 44, 1056-1058, 2015
  • A Stable iso-Bachteriochlorin Mimics from Porpholactone: Design, Synthesis and Photophysical Property.
    Y. Yu, T. Furuyama, J. Tang, Z. –Y. Wu, J. –Z. Chen, N. Kobayashi, J. –L. Zhang
    Inorg. Chem. Frontiers, 2, 671-677, 2015
  • Ring-Fused Porphyrins: Extension of π-Conjugation Significantly Affects the Aromaticity and Optical Properties of the Porphyrin π-Systems and the Lewis Acidity of the Central Metal Ions.
    Y. Saegusa, T. Ishizuka, K. Komamura, S. Shimizu, H. Kotani, N. Kobayashi, and T. Kojima
    PCCP., 17, 15001-15011, 2015
  • Synthesis and Photophysical Investigation of Tetraazaporphyrins Substituted with AIE-Active Moieties.
    T. T. Tasso, T. Furuyama, J. Mack, T. Nyokong, N. Kobayashi
    Eur. J. Inorg. Chem., 5516-5522, 2015
  • Benzo[c,d]indole-Containing aza-BODIPY: Asymmetrization-Induced Solid-State Emission and Aggregation-Induced Emission Enhancement as New Properties Derived from the Well-Known Chromophore.
    S. Shimizu, A. Murayama, T. Haruyama, T. Iino, S. Mori, H. Furuta, N. Kobayashi
    Chem. Eur. J., 21, 12996-13003, 2015
  • Solution-Cast Monolayers of Cobalt Crown Ether Phthalocyanine on Highly Ordered Pyrolytic Graphite.
    H. Lu, I. Kwak, J. H. Park, K. O'Neil, T. Furuyama, N. Kobayashi, A. Seabaugh, A. Kummel, S. F. Shirey
    J. Phys. Chem., C 119, 21992-22000, 2015
  • An Extremely Air-stable 19 Porphyrinoid.
    T. Yoshida, W. Zhou, T. Furuyama, D. B. Leznoff, N. Kobayashi
    J. Am. Chem. Soc., 137, 9258-9261, 2015
  • Silyloxy Amino Alcohol Organocatalyst for Enantioselective 1,3-Dipolar Cycloadditions of Nitrones to -Unsaturated Aldehydes.
    T. Otuki, J. Kumagai, Y. Kohari, Y. Okuyama, E. Kwon, C. Seki, K. Uwai, N. Kobayashi, T. Iwasa, M. Tokiwa, M. Takeshita, A. Maeda, A. Hashimoto, K. Turuga, H. Nakano
    Eur. J. Org. Chem., 7292-7300, 2015
  • Reducing Zirconium(IV) Phthalocyanines and the Structure of a Pc4-Zr Complex.
    W. Zhou, R. H. Platel, T. T. Tasso, T. Furuyama, N. Kobayashi, D. B. Leznoff
    Dalton Trans., 44, 13955-13961, 2015
  • A Bottom-up Synthesis of Antiaromatic Expanded Phthalocyanines: Pentabenzotriazasmaragdyrins, i.e. Norcorroles of Superphthalosyanines.
    T. Furuyama, T. Sato, N. Kobayashi
    J. Am. Chem. Soc., 137, 13788-13791, 2015
  • Modulation of the Molecular Spintronic Properties of Adsorbed Copper Corroles.
    F. Wu, J. Liu, P. Mishra, T. Komeda, J. Mack, Y. Chang, N. Kobayashi, Z. Shen
    Nature Commun., 6, 1-8, 2015電子ジャーナル

MISC

  • Optically Active Porphyrin and Phthalocyanine Systems.
    H. Lu, N. Kobayashi
    Chem. Rev., 116, 6184-6261, 2016
  • Optically Active BODIPYs
    H. Lu, J. Mack, T. Nyokong, N. Kobayashi, Z. Shen
    Coord. Chem. Rev., 318, 1-15, 2016
  • Preface: The 5th Georgian Bay International Conference on Bioinorganic Chemistry
    M. J. Stillman, N. Kobayashi, C. F. Shaw, J. Dawson
    J. Inorg. Biochem., 158, 1-4, 2016
  • Organosilicon Compounds as Fluorescent Chemosensors for the Fluoride Anion Recognition.
    L. Gai, J. Mack, H. Lu, T. Nyokong, Z. Li, N. Kobayashi, Z. Shen
    Coord. Chem. Rev., 285, 24-51, 2015
  • Design, Synthesis, and Properties of Azaporphyrin Phosphorus Complexes
    T. Furuyama, N. Kobayashi
    Journal of Synthetic Organic Chemistry, Japan, 73, 833-843, 2015
  • Properties of Phthalocyanines and Porphyrins Deduced from Their Molecular Orbitals.
    N. Kobayashi
    Chemistry of Present Days, 539, 30-35, 2015

Lectures, oral presentations, etc.

  • Synthesis and Spectroscopic Properties of P(V) Phthalocyanines and Tetraazaporphyrins.
    N. Kobayashi
    SERMACS 2016, Columbia Metropolitan Convention Center, Columbia, South Carolina, USA, Oct. 2016, Invited
  • Synthesis and Characterization of Spectroscopically Intriguing Phtghalocyanines.
    N. Kobayashi
    Unversite de Strasbourg, Strasbourg, France, 09 Sep. 2016, Invited
  • Synthesis, Applications, and Practical Use of Functional Metallophthalocyanines.
    N. Kobayashi
    Unversite de Strasbourg, Strasbourg, France, 08 Sep. 2016, Invited
  • Synthesis of TTF-annulated Silicon Phthalocyanine and Its μ-Oxo Oligomers and Redox Control of Molecular Alignment.
    N. Kobayashi
    Unversite de Strasbourg, Strasbourg, France, 07 Sep. 2016, Invited
  • CD Analysis of Optically Active Phthalocyanines, Natural Chlorophylls, and Poly(p-benzamide)s Systems.
    N. Kobayashi
    Unversite de Strasbourg, Strasbourg, France, 06 Sep. 2016, Invited
  • Synthesis and Properties of P(V) Phthalocyanines and Tetraazaporphyrins
    N. Kobayashi
    Universite de Bourgogne, Dijon, France, 02 Sep. 2016, Invited
  • Synthesis and Characterization of Spectroscopically Intriguing Phthalocyanines.
    N. Kobayashi
    ナノテク高機能テキスタイル基盤技術研究会, Shinsu Univ. Ueda, 19 Aug. 2016, Invited
  • Synthesis of Novel aza-BODIPY Analogues and Their Unique Optical and Electrochemical Properties.
    N. Kobayashi, T. Iino, A. Murayama, M. Tamada, H. Karasaki, S. Shimizu, H. Furuta
    2016 International Symposium for Metal Porphyrins and Phthalocyanines, Beijing, China, Jul. 2016, Invited
  • Investigation of the Dimerization Reaction of Phthalonitrile with Thiolate Anion and Its Application to the Synthesis of Expanded Phthalocyanines.
    N. Kobayashi, T. Sato, T. Furuyama
    The 9th International Conference on Porphyrins and Phthalocyanines, Nanjing, China, Jul. 2016, Invited
  • An Air-stable 19p Azaporphyrinoid Radical
    T. Furuyama, T. Yoshida, W. Zhou, D. B. Leznoff, N. Kobayashi
    The 9th International Conference on Porphyrins and Phthalocyanines, Nanjing, China, Jul. 2016, Invited
  • Modulation Spintronic Properties of Copper Corroles
    Z. Shen, F. Wu, N. Kobayashi, T. Komeda
    1st Dijon/Nanjing Symposium on Functional Macrocyclic Molecules, Nanjing, China, Jul. 2016, Invited
  • Synthesis and Specific Properties of P(V) Phthalocyanines and Tetraazaporphyrins
    N. Kobayashi
    1st Dijon/Nanjing Symposium on Functional Macrocyclic Molecules, Nanjing, China, Jul. 2016
  • Investigation of the Dimerization Reaction of Phthalonitrile with Thiolate Anion and Its Application to the Synthesis of Expanded Phthalocyanines.
    N. Kobayashi
    Symposium on “Phthalocyanines and Close Friends”, Instituto de Bioingeniería Universidad Miguel Hernández, Elche, Spain, Jan. 2016, Invited
  • Synthesis, Applications, and Practical Use of Functional Metallophthalocyanines
    N. Kobayashi
    Faculty of Natural Sciences, Tampere University of Technology, Tampere, Finland, Nov. 2015, Invited
  • Chemistry of Giant Aomatic Metal Complexes.
    N. Kobayashi
    Muroran Institute of Technology, Sep. 2015, Invited
  • Synthesis of Novel aza-BODIPY Analogues from a Schiff Base Formation Reaction of Lactams and Their Unique Optical and Electrochemical Properties.
    S. Shimizu, T. Iino, A. Murayama, M. Tamada, H. Karasaki, N. Kobayashi, H. Furuta
    The 16th ISNA, Complutense University, Madrid, Spain, Jul. 2015
  • Nanometer-thick Ion Conductors for 2D Crystal Memory.
    S. F. Shirey, H. Lu, W. Wang, H. Kim, I. Kwak, T. Furuyama, N. Kobayashi, K. Cho, A. Kummel, A. Seabaugh
    The 57th Electronic Materials Conference, Ohio State University, Columbus, Ohio, Jun. 2015
  • Development of Azaporphyrin Complexes with Main Group Elements.
    N. Kobayashi
    South African Chemical Institute, Inorganic Chemistry Conference 2015, Rhodes University, Grahamstown, Jun. 2015
  • Synthesis and Unique Spectroscopic Properties of Phthalocyanine and Tetraazaporphyrin Complexes with Main Group Elements.
    N. Kobayashi
    The 5th Georgian Bay International Conference on Bioinorganic Chemistry, Parry Sound, Ontario, Canada, May 2015, Invited
  • Core-Modified Porphyrins Containing Novel Heterocyclic Moieties.
    Z. Shen, Z. Zhou, Y. Chang, S. Shimizu, J. Mack, C. Schütt, R. Herges, N. Kobayashi
    The 227th ECS Meeting, Chicago, Illinois, USA, May 2015, Invited
  • Synthesis and Characterization of Spectroscopically Intriguing Phthalocyanines
    N. Kobayashi
    機能性高分子材料研究会、Shinsu Univ. Ueda, 18 Mar. 2015, Invited