SHIMIZU Masahiro

Academic Assembly School of Science and Technology Institute of Engineering

Faculty of Engineering Materials Chemistry 

Associate Professor 

Degree

  • Doctor of Engineering, Tottori University

Field Of Study

  • Electron device and electronic equipment, Development of active material for rechargeable batteries
  • Material processing and microstructure control, Control of material structure
  • Inorganic compounds and inorganic materials chemistry, Inorganic Chemistry

TEL

    +81-26-269-5627

Mail Address

    shimizu★shinshu-u.ac.jp

Career

  • 2023
    Associate Professor

Educational Background

  • 2013 - 2016, Tottori University, Graduate School of Engineering, Department of Chemistry and Biotechnology

Member History

  • 2021
    幹事, 日本材料科学会先端ウェットプロセス研究会
  • 2018 - 2019
    中部支部 幹事, 日本分析化学会

Paper

  • Lithiation/Delithiation of Silicon Heavily Doped with Boron Synthesized Using the Czochralski Process
    M. Shimizu, K. Kimoto, A. Kikuchi, T. Taishi, S. Arai
    Energy Advances, 2, 813-819, 2023
    Lead, Corresponding
  • Cation-Structure Effects on Zinc Electrodeposition and Crystallographic Orientation in Ionic Liquids
    M. Shimizu, Y. Sugiyama, M. Horita, K. Yoshii, S. Arai
    ChemElectroChem, 9(10), e202200357, 2022
    Lead, Corresponding
  • Intercalation/deintercalation of solvated Mg2+ into/from graphite interlayers
    M. Shimizu, A. Nakahigashi, S. Arai
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, (23), 16981-16988, 2021
  • Ligand Exchange Conduction of Lithium Ion in a Pentaglyme- Lithium Bis(trifluoromethylsulfonyl)amide Super-Concentrated Electrolyte
    A. Kitada, K. Kawata, M. Shimizu, M. Saimura, T. Nagata, M. Katahira, K. Fukami, K. Murase
    Journal of The Electrochemical Society, 168, 016506, 2021電子ジャーナル
  • A phosphonium ylide as a visible light organophotoredox catalyst
    Y. Toda, K. Tanaka, R. Matsuda, T. Sakamoto, S. Katsumi, M. Shimizu, F. Ito, H. Suga
    Chemical Communications, 57, 3591-3594, 2021電子ジャーナル
  • Dopant Effect on Lithiation/Delithiation of Highly Crystalline Silicon Synthesized Using the Czochralski Process
    M. Shimizu, K. Kimoto, T. Kawai, T. Taishi, S. Arai
    ACS Applied Energy Materials, 4(8), 7922-7929, 2021電子ジャーナル
  • Fabrication of Roughened Electrodeposited Copper Coating on Steel for Dissimilar Joining of Steel and Thermoplastic Resin
    S. Arai, R. Iwashita, M. Shimizu, J. Inoue, M. Horita, T. Nagaoka, M. Itabashi
    Metals, 11(4), 591, 2021WebofScienceリポジトリ電子ジャーナル
  • Superior electrical contact characteristics of Ag/CNT composite films formed in a cyanide-free plating bath and tested against corrosion by H2S gas
    S. Arai, T. Kikuhara, M. Shimizu, M. Horita
    Materials Letters, 303, 130504, 2021リポジトリ電子ジャーナル
  • Dispersion of multiwalled carbon nanotubes into a diglyme solution, electrodeposition of aluminum-based composite, and improvement of hardness
    Z. Zhang, A. Kitada, T. Chen, K. Fukami, M. Shimizu, S. Arai, Z. Yao, K. Murase
    Journal of Alloys and Compounds, 816, 152585, 2020
  • Multi-layered copper foil reinforced by co-deposition of single-walledcarbon nanotube based on electroplating technique
    M. Shimizu, T. Ogasawara, T. Ohnuki, S. Arai
    Materials Letters, 261, 126993, 2020
  • Excellent bonding strength between steel and thermoplastic resin using roughened electrodeposited Ni/CNT composite layer without adhesives
    S. Arai, R. Sugawara, M. Shimizu, J. Inoue, M. Horita, T. Nagaoka, M. Itabashi
    Materials Letters, 263, 127241, 2020
  • Piperidinium-based Ionic Liquids as an Electrolyte Solvent for Li-Ion Batteries: Effect of Number and Position of Oxygen Atom in Cation Side Chain on Electrolyte Property
    M. Shimizu, K. Yamaguchi, H. Usui, N. Ieuji, T. Yamashita, T. Komura, Y. Domi, T. Nokami, T. Itoh, H. Sakaguchi
    Journal of The Electrochemical Society, 167, 070516, 2020
  • Kinetics Study and Degradation Analysis through Raman Spectroscopy of Graphite as a Negative-Electrode Material for Potassium-Ion Batteries
    M. Shimizu, T. Koya, A. Nakahigashi, N. Urakami, T. Yamakami, S. Arai
    The Journal of Physical Chemistry C, 2020
  • Superior Durability of Dissimilar Material Joint between Steel and Thermoplastic Resin with Roughened Electrodeposited Nickel Interlayer
    S. Arai, R. Sugawara, M. Shimizu, J. Inoue, M. Horita, T. Nagaoka, M. Itabashi
    Advanced Engineering Materials, 22(12), 2000739, 2020WebofScienceリポジトリ電子ジャーナル
  • Electrodeposition of Ag/CNT Composite Films from Iodide Plating Baths
    S. Arai, T. Kikuhara, M. Shimizu, M. Horita
    Journal of The Electrochemical Society, 167(12), 122515, 2020WebofScienceリポジトリ電子ジャーナル
  • Fabrication of CNT/Cu Composite Yarn via Single-Step Electrodeposition
    S. Arai, I. Murakami, M. Shimizu, A. Oshigane
    Journal of The Electrochemical Society, 167(10), 102509, 2020WebofScienceリポジトリ電子ジャーナル
  • Morphology control of zinc electrodeposition by surfactant addition for alkaline-based rechargeable batteries
    M. Shimizu, K. Hirahara, S. Arai
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 21, 7045–7052, 2019
  • Effect of Film-Forming Additive in Ionic Liquid Electrolyte on Electrochemical Performance of Si Negative-Electrode for LIBs
    K. Yamaguchi, Y. Domi, H. Usui, M. Shimizu, S. Morishita, S. Yodoya, T. Sakata, H. Sakaguchi
    Journal of The Electrochemical Society, 166(2), A268–A276, 2019
  • Alkyl-Chain-Length Dependence of Quaternary Ammonium Cation on Zn Deposition Morphology in Alkaline-based Electrolytes
    M. Shimizu, K. Hirahara, Y. Ishida, S. Arai
    Journal of The Electrochemical Society, 166(10), A2242–A2244, 2019
  • Electrodeposited Cu/MWCNT composite-film: a potential current collector of silicon-based negative-electrodes for Li-ion batteries
    M. Shimizu, T. Ohnuki, T. Ogasawara, T. Banno, S. Arai
    RSC Advances, 9, 21939–21945, 2019
  • Effects of the ether oxygen atom in alkyl side chains on the physical properties of piperidinium ionic liquids
    T. Nokami, T. Yamashita, T. Komura, N. Handa, M. Shimizu, K. Yamaguchi, Y. Domi, H. Usui, H. Sakaguchi, T. Itoh
    Faraday Discussions, 206, 523–534, 2018
  • Tin Oxides as a Negative Electrode Material for Potassium-Ion Batteries
    M. Shimizu, R. Yatsuzuka, T Koya, T. Yamakami, S. Arai
    ACS Applied Energy Materials, 1(12), 6865–6870, 2018
  • Intercalation/De-intercalation Behavior of Li-ion Encapsulated by 12-Crown-4-Ether into Graphite Electrode
    M. Shimizu, T. Koya, M. Umeki, S. Arai
    Journal of The Electrochemical Society, 165(13), A3212–A3214, 2018
  • Suppressing the effect of lithium dendritic growth by the addition of magnesium bis(trifluoromethanesulfonyl)amide
    M. Shimizu, M. Umeki, S. Arai
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 20(2), 1127–1133, 2018WebofScienceリポジトリ電子ジャーナル
  • Electrochemical preparation of free-standing carbon-nanotube/Sn composite paper
    M. Shimizu, S. Shimizu, A. Katada, M. Uejima, S. Arai
    Materials Letters, 220, 182–185, 2018WebofScienceリポジトリ電子ジャーナル
  • Influence of the structure of the anion in an ionic liquid electrolyte on the electrochemical performance of a silicon negative electrode for a lithium-ion battery
    K. Yamaguchi, Y. Domi, H. Usui, M. Shimizu, K. Matsumoto, T. Nokami, T. Itoh, H. Sakaguchi
    Journal of Power Sources, 338, 103−107, 2017, Refereed
  • Charge−Discharge Properties of a Sn4P3 Negative Electrode in Ionic Liquid Electrolyte for Na-Ion Batteries
    H. Usui, Y. Domi, K. Fujiwara, M. Shimizu, T. Yamamoto, T. Nohira, R. Hagiwara, H. Sakaguchi
    ACS Energy Letters, 2(5), 1139−1143, 2017
  • Electrochemical Na-Insertion/Extraction Propertyof Ni-Coated Black Phosphorus Prepared by an Electroless Deposition Method
    M. Shimizu, Y. Tsushima, S. Arai
    ACS OMEGA, 2(8), 4306–4315, 2017
  • Fabrication of Copper/Single-Walled Carbon Nanotube Composites by Electrodeposition using Free-Standing Nanotube Film
    S. Arai, K. Kirihata, M. Shimizu, M. Ueda, A. Katada, M. Uejima
    Journal of The Electrochemical Society, 164(13), D922–D929, 2017, Refereed
  • Design of Roughened Current Collector by Bottom-Up Approach Using Electroplating Technique: Charge–Discharge Performance of Sn Negative-Electrode for Na-Ion Batteries
    M. Shimizu, R. Yatsuzuka, M. Horita, T. Yamamoto, S. Arai
    The Journal of Physical Chemistry C, 121(49), 27285–27294, 2017, Refereed
  • Li-insertion/extraction properties of three-dimensional Sn electrode prepared by facile electrodeposition method
    M. Shimizu, M. Munkhbat, S. Arai
    Journal of Applied Electrochemistry, 47(6), 727−734, 2017WebofScienceリポジトリ電子ジャーナル
  • Micro-Scale Columnar Architecture Composed of Copper Nano Sheets by Electrodeposition Technique
    S. Arai, M. Ozawa, M. Shimizu
    Journal of The Electrochemical Society, 164(2), D72−D74, 2017WebofScienceリポジトリ電子ジャーナル
  • Effect of Phosphorous-Doping on Electrochemical Performance of Silicon Negative-Electrodes in Lithium-Ion Batteries
    Y. Domi, H. Usui, M. Shimizu, Y. Kakimoto, and H. Sakaguchi
    ACS Applied Materials & Interfaces, 8(11), 7125−7132, 2016
  • Functional ionic liquid for enhancement of Li-ion transfer: Effect of cation structure on charge-discharge performance of Li4Ti5O12 electrode
    M. Shimizu, H. Usui, H. Sakaguchi
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 18, 5139−5147, 2016
  • Niobium-doped titanium oxide anode and ionic liquid electrolyte for a safe sodium-ion battery
    H. Usui, Y. Domi, M. Shimizu, A. Imoto, K. Yamaguchi, H. Sakaguchi
    Journal of Power Sources, 329, 428−431, 2016
  • Fabrication of Three-Dimensional (3D) Copper/Carbon Nanotube Composite Film by One-Step Electrodeposition
    S. Arai, M. Ozawa, M. Shimizu
    Journal of The Electrochemical Society, 163(14), D774−D779, 2016, RefereedWebofScienceリポジトリ電子ジャーナル
  • Analysis of the Deterioration Mechanism of Si Electrode as a Li-Ion Battery Anode Using Raman Microspectroscopy
    M. Shimizu, H. Usui, T. Suzumura, H. Sakaguchi
    The Journal of Physical Chemistry C, 119(6), 2975−2982, 2015
  • Nb-Doped Rutile TiO2: a Potential Anode Material for Na-Ion Battery
    H. Usui, S. Yoshioka, K. Wasada, M. Shimizu, H. Sakaguchi
    ACS Applied Materials & Interfaces, 7(12), 6567−6573, 2015
  • Electrochemical Na-insertion/extraction properties of Sn-P anodes
    H. Usui, T. Sakata, M. Shimizu, and H. Sakaguchi
    Electrochemistry, 83(10), 810−812, 2015
  • Electrochemical behavior of SiO as an anode material for Na-ion battery
    M. Shimizu, H. Usui, K. Fujiwara, K. Yamane, H. Sakaguchi
    Journal of Alloys and Compounds, 640, 440-443, 2015
  • Effect of Film-forming Additive on Electrochemical Performance of Silicon Negative-Electrode in Lithium-Ion Batteries
    Y. Domi, H. Usui, M. Shimizu, K. Miwa, H. Sakaguchi
    International Journal of Electrochemical Science, 10, 9678−9686, 2015
  • Electrochemical Na-Insertion/Extraction Properties of Phosphorus Electrodes in Ionic Liquid Electrolytes
    M. Shimizu, H. Usui, K. Yamane, T. Sakata, T. Nokami, T. Itoh, H. Sakaguchi
    International Journal of Electrochemical Science, 10, 10132−10144, 2015
  • Effect of cation structure of ionic liquid on anode properties of Si electrodes for LIB
    M. Shimizu, H. Usui, K. Matsumoto, T. Nokami, T. Itoh, H. Sakaguchi
    Journal of The Electrochemical Society, 161(12), A1765−A1771, 2014
  • Electrochemical Na-insertion/extraction properties of SnO thick-film electrodes prepared by gas-deposition
    M. Shimizu, H. Usui, H. Sakaguchi
    Journal of Power Sources, 248, 378−382, 2014
  • Applicability of ionic liquid electrolytes to LaSi2/Si composite thick-film anodes in Li-ion battery
    H. Usui, M. Shimizu, H. Sakaguchi
    Journal of Power Sources, 235, 29−35, 2013
  • TiO2/Si composites synthesized by sol–gel method and their improved electrode performance as Li-ion battery anodes
    H. Usui, K. Wasada, M. Shimizu, H. Sakaguchi
    Electrochimica Acta, 111, 575−580, 2013

Books and other publications

  • 多価カチオンのインターカレーションとその 電池反応への応用可能性(ポストリチウムイオン電池の開発動向と実用化への課題)
    清水雅裕, Single work
    月刊 車載テクノロジー,技術情報協会, 2022
  • 化学同人:化学(月刊)注目の論文:リチウムを使わない次世代の二次電池:電気化学デバイスにおけるキャリアイオンの多様性
    清水雅裕, Joint work, リチウムを使わない次世代の二次電池:電気化学デバイスにおけるキャリアイオンの多様性
    化学同人, Dec. 2019
  • カーボンナノチューブの表面処理・分散技術と複合化事例
    清水雅裕,新井 進, Joint work, 第7章 第3節 カーボンナノチューブ複合めっき基板の集電体への応用
    技術情報協会, Dec. 2019
  • リチウムイオン二次電池用シリコン系負極材の開発動向
    清水雅裕,新井 進, Joint work, 第 II 編 第3章 シリコン負極用高比表面積銅系集電体
    CMC出版, Nov. 2019
  • リチウムイオン二次電池用炭素系負極材の開発動向
    清水雅裕,新井 進, Joint work, 第 II 編 第7章 めっき技術を用いたリチウムイオン電池用CNT/Sn電極の開発
    CMC出版, Sep. 2019
  • 次世代電池用電極材料の高エネルギー密度、高出力化-リチウム過剰系正極、三元系正極、シリコン系負極、ポストリチウムイオン電池-
    清水雅裕,新井 進, 第10章 第3節 集電体一体型ナトリウムイオン二次電池負極の創製
    情報技術協会, Nov. 2017
  • 最新フォトレジスト材料開発とプロセス最適化技術セス最適化技術
    新井 進,清水雅裕, Joint work, 第V編 第1章 フォトレジストを用いた電気めっき法による微細プロセス最適化技術
    CMC出版, Sep. 2017

Affiliated academic society

  • 2017
    日本分析化学会
  • 2016
    The Electrochemical Society (ECS)
  • 2016
    The Electrochemical Society of Japan
  • 2016
    The Chemical Society of Japan
  • 2016
    The surface finishing society of japan
  • 2016
    The Rare Earth Society of Japan

Research Themes

  • 非シアン浴を用いたAg-Bi合金/CNT複合めっき膜の創製
    科学研究費補助金, 基盤研究C
    2022 - 2024
  • 対極電位から再考するマグネシウム二次電池負極としての黒鉛の可能性
    科学研究費補助金, 基盤研究(B)
    2020 - 2022
  • 溶媒和イオンのインターカレーションに基づく多価カチオン電池の創製(公益財団法人TAKEUCHI育英奨学会)
    2019 - 2020
  • 公益財団法人矢崎科学技術振興記念財団 国際交流援助
    2019
  • 包摂型多価カチオンを用いた析出形態制御に基づくリチウム金属二次電池の長寿命化(公益財団法人浦上奨学会 研究助成)
    2019
  • 亜鉛の析出形態制御に基づく高性能空気電池の開発(公益財団法人八洲環境技術振興財団 研究助成)
    公益財団法人八洲環境技術振興財団
    2019
  • 高性能金属空気電池の実現に向けたZnの析出形態制御
    科学研究費補助金, 若手研究
    2018 - 2019
  • 高効率小型熱交換器用Niブレージング電解膜の創製(A-STEP機能検証フェーズ 試験研究タイプ 平成30年度第1回公募)/分担
    2018 - 2019
  • 金属空気電池の高性能化に向けた亜鉛の析出形態制御(池谷科学技術振興財団)
    2018
  • 公益社団法人電気化学会 若手研究者の国際交流支援(平成30年度 前期)
    2018
  • 銅/カーボンナノチューブ共析膜の電気化学的創製とリチウムイオン電池への展開(新素材情報財団)
    2017
  • カーボンナノチューブ/スズ自立膜複合体の電気化学的創製とリチウムイオン電池への応用(村田学術振興財団)
    2017
  • 溶媒和イオンのインターカレーションを積極的に利用した高速充放電可能な多価カチオン電池の創製(本多英五郎研究助成)
    2017
  • めっき法による三次元多孔質構造を有する集電体一体型ナトリウム二次電池負極の創製
    科学研究費補助金, 研究活動スタート支援
    2016 - 2017
  • 無電解めっき法を活用した高容量ナトリウムイオン電池用リン系負極の開発(本多英五郎研究助成)
    2016
  • めっき法による三次元多孔質銅集電体の開発とナトリウムイオン電池負極への展開(信州大学工学部若里会)
    2016
  • アルカリ金属イオン二次電池負極材料の創製とそれを活かす機能性界面の構築
    科学研究費補助金, 特別研究員奨励費
    2015 - 2016
  • アルカリ金属イオン二次電池負極材料の創製(鳥取大学エンカレッジファンド)
    2014