戸田 泰徳 (トダ ヤスノリ)
学術研究院（工学系）
工学部 物質化学科
准教授
研究者情報
研究キーワード
- 有機合成化学, 有機分子触媒
電話番号
- 026-269-5390
メールアドレス
- ytoda★shinshu-u.ac.jp
研究活動情報
受賞
論文
- Mechanistic Insights into Urea-, Thiourea-, and Isothiourea-Based Bifunctional Tetraarylphosphonium Salt Catalysis for Conversion of Carbon Dioxide to Cyclic Carbonates
Toda, Yasunori; Suenaga, Daiki; Yamaguchi, Ren; Suga, Hiroyuki;
European Journal of Organic Chemistry, 27(16), e202400137, 2024年
- Asymmetric Inverse-Electron-Demand 1,3-Dipolar Cycloadditions Using Organocatalysts
Suga, Hiroyuki; Toda, Yasunori;
Heterocycles, 106, 1649-1686, 2023年 - Base-mediated synthesis of cyclic dithiocarbamates from 1-amino-3-chloropropan-2-ol derivatives and carbon disulfide
Toda, Yasunori; Iwasaki, Masaya; Suga, Hiroyuki;
Organic & Biomolecular Chemistry, 21(31), 6293-6297, 2023年 - Visible-Light-Driven C-H Imidation of Arenes and Heteroarenes by a Phosphonium Ylide Organophotoredox Catalyst: Application to C-H Functionalization of Alkenes
Toda, Yasunori; Kobayashi, Toya; Hirai, Fumiya; Yano, Takamichi; Oikawa, Makoto; Sukegawa, Kimiya; Shimizu, Masahiro; Ito, Fuyuki; Suga, Hiroyuki;
The Journal of Organic Chemistry, 88(13), 9574-9578, 2023年 - Ring-fused hexahydro-1,2,4,5-tetrazines: synthesis, structure, and mechanistic studies on isolable rotational isomers
Toda, Yasunori; Kooguchi, Airi; Sukegawa, Kimiya; Kikuchi, Ayaka; Suga, Hiroyuki;
Chemical Communications, 59(6), 700-703, 2023年 - Development of Phosphonium Ylides as Multifunctional Organocatalysts
Toda, Yasunori; Suga, Hiroyuki;
JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 81(4), 333-340, 2023年 - Tetraarylphosphonium salt-catalyzed formal [3+2] cycloaddition between epoxides and trichloroacetonitrile for the synthesis of β-amino alcohol derivatives
Toda, Yasunori; Shiokawa, Ryota; Iwasaki, Masaya; Yamaguchi, Daisuke; Kawamura, Keisuke; Sukegawa, Kimiya; Suga, Hiroyuki;
Chemical Communications, 58(84), 11819-11822, 2022年 - Asymmetric Cycloadditions of Acyclic Carbonyl Ylides with Aldehydes Catalyzed by a Chiral Binaphthyldiimine-Ni(II) Complex: Enantioselective Synthesis of 1,3-Dioxolanes and Mechanistic Studies by DFT Calculations
Toda, Yasunori; Sato, Kayo; Sato, Kensuke; Nagasaki, Kazuma; Nakajima, Hirotaka; Kikuchi, Ayaka; Sukegawa, Kimiya; Suga, Hiroyuki;
ORGANIC LETTERS, 24(26), 4739-4744, 2022年 - Dynamic parallel kinetic resolution of alpha-ferrocenyl cation initiated by chiral Bronsted acid catalyst
Toda, Yasunori; Korenaga, Toshinobu; Obayashi, Ren; Kikuchi, Jun; Terada, Masahiro;
Chemical Science, 12(30), 10306-10312, 2021年 - Switchable synthesis of cyclic carbamates by carbon dioxide fixation at atmospheric pressure
Toda, Yasunori; Shishido, Minoru; Aoki, Tatsuya; Sukegawa, Kimiya; Suga, Hiroyuki;
Chemical Communications, 57(54), 6672-6675, 2021年 - A phosphonium ylide as a visible light organophotoredox catalyst
Toda, Yasunori; Tanaka, Katsumi; Matsuda, Riki; Sakamoto, Tomoyuki; Katsumi, Shiho; Shimizu, Masahiro; Ito, Fuyuki; Suga, Hiroyuki;
Chemical Communications, 57(29), 3591-3594, 2021年 - Enantioselective Protonation of Cyclic Carbonyl Ylides by Chiral Lewis Acid Assisted Alcohols
Toda, Yasunori; Yoshida, Takayuki; Arisue, Kaoru; Fukushima, Kazuaki; Esaki, Hiroyoshi; Kikuchi, Ayaka; Suga, Hiroyuki;
CHEMISTRY-A EUROPEAN JOURNAL, 27(41), 10578-10582, 2021年 - 二官能性テトラアリールホスホニウム塩触媒の設計
戸田泰徳、菅博幸
TCIメール No.183, 2020年 - Synthesis of 1,2,5-Oxadiazinane Derivatives by Photochemical Cycloaddition of Nitrones with Diaminomethanes
Itoh, Kennosuke; Takashino, Atsushi; Ohtsuka, Atsushi; Kobe, Mizuki; Sawamura, Shunsuke; Kato, Ryo; Hirayama, Shigeto; Karaki, Fumika; Mizuguchi, Takaaki; Sato, Noriko; Tokunaga, Ken; Toda, Yasunori; Suga, Hiroyuki; Ishida, Hitoshi; Fujii, Hideaki;
CHEMPHOTOCHEM, 2020年 - A Phosphonium Ylide as a Ligand for [3+2] Coupling Reactions of Epoxides with Heterocumulenes under Mild Conditions
Toda, Yasunori; Hashimoto, Kousuke; Mori, Yoko; Suga, Hiroyuki;
JOURNAL OF ORGANIC CHEMISTRY, 85(16), 10980-10987, 2020年 - Visible-light-triggered Catalytic Halohydrin Synthesis from Epoxides and Trichloroacetonitrile by Copper and Iron Salts
Toda, Yasunori; Tanaka, Katsumi; Matsuda, Riki; Suga, Hiroyuki;
Chemistry Letters, 48(12), 1469-1471, 2019年12月 - Catalytic Asymmetric 1,3-Dipolar Cycloaddition Reactions Based on Ylide Formation Reactions
Suga, Hiroyuki; Toda, Yasunori;
JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 77(10), 1014-1022, 2019年10月 - Methoxy Groups Increase Reactivity of Bifunctional Tetraarylphosphonium Salt Catalysts for Carbon Dioxide Fixation: A Mechanistic Study
Toda, Yasunori; Komiyama, Yutaka; Esaki, Hiroyoshi; Fukushima, Kazuaki; Suga, Hiroyuki;
JOURNAL OF ORGANIC CHEMISTRY, 84(23), 15578-15589, 2019年 - 4-Hydroxymethyl-substituted oxazolidinone synthesis by tetraarylphosphonium salt-catalyzed reactions of glycidols with isocyanates
Toda, Yasunori; Tanaka, Shoya; Gomyou, Shuto; Kikuchi, Ayaka; Suga, Hiroyuki;
Chemical Communications, 55(41), 5761-5764, 2019年 - Use of trichloroacetonitrile as a hydrogen chloride generator for ring-opening reactions of aziridines
Toda, Yasunori; Matsuda, Riki; Gomyou, Shuto; Suga, Hiroyuki;
Organic & Biomolecular Chemistry, 17(15), 3825-3829, 2019年 - Enantioselective synthesis of 8-azabicyclo[3.2.1]octanes via asymmetric 1,3-dipolar cycloadditions of cyclic azomethine ylides using a dual catalytic system
Suga, Hiroyuki; Yoshiwara, Masahiro; Yamaguchi, Takaaki; Bando, Takashi; Taguchi, Mizuki; Inaba, Ayano; Goto, Yuichi; Kikuchi, Ayaka; Itoh, Kennosuke; Toda, Yasunori;
Chemical Communications, 55(11), 1552-1555, 2019年 - ENANTIOSELECTIVE CYCLOADDITIONS BETWEEN ALIPHATIC NITRILE OXIDES AND 2-HYDROXYSTYRENES CATALYZED BY CHIRAL AMINE-UREA
Toda, Yasunori; Koyama, Masato; Esaki, Hiroyoshi; Fukushima, Kazuaki; Suga, Hiroyuki;
Heterocycles, 97(1), 147-150, 2018年 - Triethylamine Enables Catalytic Generation of Oxidopyrylium Ylides for [5+2] Cycloadditions with Alkenes: An Efficient Entry to 8-Oxabicyclo[3.2.1]octane Frameworks
Toda, Yasunori; Shimizu, Masahiro; Iwai, Taichi; Suga, Hiroyuki;
ADVANCED SYNTHESIS & CATALYSIS, 360(12), 2377-2381, 2018年 - Three-Component Reactions of Diazoesters, Aldehydes, and Imines Using a Dual Catalytic System Consisting of a Rhodium(II) Complex and a Lewis Acid
Toda, Yasunori; Kaku, Wakatake; Tsuruoka, Makoto; Shinogaki, Sho; Abe, Tomoka; Kamiya, Hideaki; Kikuchi, Ayaka; Itoh, Kennosuke; Suga, Hiroyuki;
ORGANIC LETTERS, 20(9), 2659-2662, 2018年 - Efficient generation of an oxidopyrylium ylide using a Pd catalyst and its [5+2] cycloadditions with several dipolarophiles
Suga, Hiroyuki; Iwai, Taichi; Shimizu, Masahiro; Takahashi, Kie; Toda, Yasunori;
Chemical Communications, 54(9), 1109-1112, 2018年 - Tetraarylphosphonium Salt-Catalyzed Synthesis of Oxazolidinones from Isocyanates and Epoxides
Toda, Yasunori; Gomyou, Shuto; Tanaka, Shoya; Komiyama, Yutaka; Kikuchi, Ayaka; Suga, Hiroyuki;
ORGANIC LETTERS, 19(21), 5786-5789, 2017年 - A Phosphonium Ylide as an Ionic Nucleophilic Catalyst for Primary Hydroxyl Group Selective Acylation of Diols
Toda, Yasunori; Sakamoto, Tomoyuki; Komiyama, Yutaka; Kikuchi, Ayaka; Suga, Hiroyuki;
ACS CATALYSIS, 7(9), 6150-6154, 2017年 - Amine-Urea-Mediated Asymmetric Cycloadditions between Nitrile Oxides and o-Hydroxystyrenes by Dual Activation
Suga, Hiroyuki; Hashimoto, Yohei; Toda, Yasunori; Fukushima, Kazuaki; Esaki, Hiroyoshi; Kikuchi, Ayaka;
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 56(39), 11936-11939, 2017年 - Tetraarylphosphonium Salt-Catalyzed Carbon Dioxide Fixation at Atmospheric Pressure for the Synthesis of Cyclic Carbonates
Toda, Yasunori; Komiyama, Yutaka; Kikuchi, Ayaka; Suga, Hiroyuki;
ACS CATALYSIS, 6(10), 6906-6910, 2016年 - Enantioconvergent Nucleophilic Substitution Reaction of Racemic Alkyne-Dicobalt Complex (Nicholas Reaction) Catalyzed by Chiral Bronsted Acid
Terada, Masahiro; Ota, Yusuke; Li, Feng; Toda, Yasunori; Kondoh, Azusa;
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 138(34), 11038-11043, 2016年 - Chiral Lewis Acid-Catalyzed Enantioselective Cycloadditions between Indoles and Cyclic Carbonyl Ylides Derived from Diazodiketone or Diazoketoester Derivatives
Suga, Hiroyuki; Sekikawa, Yurie; Misawa, Shunta; Kinugawa, Daito; Oda, Rinnosuke; Itoh, Kennosuke; Toda, Yasunori; Kiyono, Ryotaro;
JOURNAL OF ORGANIC CHEMISTRY, 80(13), 6687-6696, 2015年 - Bronsted Acid Catalyzed Phosphoramidic Acid Additions to Alkenes: Diastereo- and Enantioselective Halogenative Cyclizations for the Synthesis of C- and P-Chiral Phosphoramidates
Toda, Yasunori; Pink, Maren; Johnston, Jeffrey N.;
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 136(42), 14734-14737, 2014年 - Secondary stereocontrolling interactions in chiral Bronsted acid catalysis: study of a Petasis-Ferrier-type rearrangement catalyzed by chiral phosphoric acids
Kanomata, Kyohei; Toda, Yasunori; Shibata, Yukihiro; Yamanaka, Masahiro; Tsuzuki, Seiji; Gridnev, Ilya D.; Terada, Masahiro;
Chemical Science, 5(9), 3515-3523, 2014年 - Mechanistic Studies of Highly Enantio- and Diastereoselective Aza-Petasis-Ferrier Rearrangement Catalyzed by Chiral Phosphoric Acid
Terada, Masahiro; Komuro, Takazumi; Toda, Yasunori; Korenaga, Toshinobu;
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 136(19), 7044-7057, 2014年 - Chiral Silver Phosphate Catalyzed Transformation of ortho-Alkynylaryl Ketones into 1H-Isochromene Derivatives through an Intramolecular-Cyclization/Enantioselective-Reduction Sequence
Terada, Masahiro; Li, Feng; Toda, Yasunori;
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 53(1), 235-239, 2014年 - Chiral Anion Catalysis in the Enantioselective 1,4-Reduction of the 1-Benzopyrylium Ion as a Reactive Intermediate
Terada, Masahiro; Yamanaka, Takuto; Toda, Yasunori;
CHEMISTRY-A EUROPEAN JOURNAL, 19(41), 13658-13662, 2013年 - Relay Catalysis by a Ruthenium Complex-Chiral Bronsted Acid Binary Sytem for Ternary Reaction Sequence Involving Enantioselective Pictet-Spengler-Type Cyclization as the Key Step
Toda, Yasunori; Terada, Masahiro;
Synlett, 24(6), 752-756, 2013年 - Relay Catalysis Using a Rhodium Complex/Chiral Bronsted Acid Binary System: Enantioselective Reduction of a Carbonyl Ylide as the Reactive Intermediate
Terada, Masahiro; Toda, Yasunori;
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 51(9), 2093-2097, 2012年 - Double Bond Isomerization/Enantioselective Aza-Petasis-Ferrier Rearrangement Sequence as an Efficient Entry to Anti- and Enantioenriched beta-Amino Aldehydes
Terada, Masahiro; Toda, Yasunori;
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 131(18), 6354-6355, 2009年
共同研究・競争的資金等の研究課題
- リンイリド可視光レドックス触媒によるアリールラジカルの反応開発
科学研究費補助金, 基盤研究(C)
2024年 - 2026年 - 一般財団法人 信州大学工学部若里会 研究助成
2024年 - 公益財団法人 ノバルティス科学振興財団 研究助成
2023年 - 有機分子触媒下での逆電子要請型不斉1,3-双極性付加環化反応-方法論の開拓と確立
科学研究費補助金, 基盤研究(C)
2022年 - 2024年 - 公益財団法人 上原記念生命科学財団 研究助成
2022年 - 可視光応答型新規有機光レドックス触媒の設計開発
科学研究費補助金, 基盤研究(C)
2021年 - 2023年 - 一般社団法人 信州大学みらい産業共創会 研究助成
2020年 - 「金属／酸」ハイブリッド触媒系における双極性化合物の立体選択的反応の開発
科学研究費補助金, 基盤研究(C)
2019年 - 2021年 - 水素結合ドナー・ホスホニウム塩複合型有機分子触媒の設計開発
科学研究費補助金, 若手研究(B)
2017年 - 2019年 - 計算化学的スクリーニングを利用した有機分子触媒反応の設計および開発
科学研究費補助金, 基盤研究(C)
2017年 - 2019年 - 公益財団法人 服部報公会 研究助成
2017年 - ホスホニウムベタインを用いたデザイン型マルチ機能触媒の設計開発
科学研究費補助金, 研究活動スタート支援
2015年 - 2016年
