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撹上将規  カキアゲ マサキ

教員組織学術研究院(繊維学系)電話番号
教育組織先鋭領域融合研究群 国際ファイバー工学研究所FAX番号
職名助教メールアドレスkakiage@shinshu-u.ac.jp
住所〒386-8567 長野県上田市常田3-15-1ホームページURLhttp://fiber.shinshu-u.ac.jp/kakiage/index.html

プロフィール

研究分野
無機工業材料
高分子・繊維材料
キーワード:セラミックス , 高分子構造・物性 , 繊維
現在の研究課題
有機化合物を用いた前駆体構造制御によるホウ化物粉末の低温合成
キーワード:低温合成 , 前駆体構造 , ポリオール , 炭化ホウ素(B4C) , ホウ化物粉末
高分子を用いた形態機能性セラミックスの作製
キーワード:セラミックス , 高分子 , 構造組織化 , 多孔体
分子鎖絡み合い特性を利用した構造形成による繊維・フィルム材料の高性能化・高機能化
キーワード:紡糸 , 分子鎖絡み合い , 結晶構造
所属学会
所属学会
高分子学会
日本放射光学会
繊維学会
日本化学会
日本セラミックス協会
無機マテリアル学会
学歴
出身大学院
2008 , 群馬大学 , 工学研究科 , 物質工学専攻
2006 , 群馬大学 , 工学研究科 , 材料工学専攻

出身学校・専攻等(大学院を除く)
2004 , 群馬大学 , 工学部 , 材料工学科

取得学位
博士(工学) , 群馬大学
受賞学術賞
2018 , 第72回(2017年度)日本セラミックス協会賞(進歩賞)
2015 , 日本セラミックス協会第28回秋季シンポジウム グリーン・プロセッシングによる機能性セラミックスの新展開セッション・優秀賞
2007 , Award for the Best Presentation, The 2nd Gunma International Symposium on Chemistry
2007 , 愛知県若手研究者奨励事業第1回「わかしゃち奨励賞」・最優秀賞
研究職歴等
研究職歴
2018- , 信州大学先鋭領域融合研究群国際ファイバー工学研究所 助教
2015-2018 , 信州大学先鋭領域融合研究群国際ファイバー工学研究所 助教(特定雇用)
2009-2015 , 埼玉大学大学院理工学研究科 助教
2009-2009 , 東京工業大学大学院理工学研究科 産学官連携研究員
2008-2009 , 日本学術振興会特別研究員PD(東京工業大学)
2007-2008 , 日本学術振興会特別研究員DC2(群馬大学)

研究活動業績

研究業績(著書・
発表論文等)
著書
超高分子量ポリエチレンの溶融超延伸過程におけるインプロセス計測とフィルム高性能化
高分子の結晶化制御‐研究開発の最前線とその応用‐ , :114-126 2012(Jul.)
Author:上原宏樹、撹上将規、山延健


論文
Low-temperature synthesis of boride powders by controlling microstructure in precursor using organic compounds
Journal of the Ceramic Society of Japan,126(8):602-608 2018
Author:Masaki Kakiage


Effect of calcium carbonate particle size on formation and morphology of calcium hexaboride powder synthesized from condensed boric acid-poly(vinyl alcohol) product
Advanced Powder Technology,29(1):36-42 2018
Author:Masaki Kakiage, Shuhei Shiomi, Tomoyo Ohashi, and Hidehiko Kobayashi


Fabrication of three-dimensional interconnected nanoporous hydroxyapatite by freeze-thaw process of amorphous calcium phosphate-poly(vinyl alcohol) gel
Journal of Alloys and Compounds,696:566-571 2017
Author:Masaki Kakiage, Yuta Hatanaka, and Hidehiko Kobayashi


Low-temperature carbothermal nitridation of boron oxide induced by networked carbon structure
Journal of the Ceramic Society of Japan,124(1):13-17 2016
Author:Masaki Kakiage, Toru Shoji, and Hidehiko Kobayashi


酸化ホウ素‐炭素構造体が拓く低温熱炭素還元法
CACS FORUM,6:22-25 2015
Author:撹上将規、小林秀彦


Low-Temperature Synthesis of Calcium Hexaboride Powder via Transient Boron Carbide Formation
Journal of the American Ceramic Society,98(9):2724-2727 2015
Author:Masaki Kakiage, Shuhei Shiomi, Ikuo Yanase, and Hidehiko Kobayashi


Effect of citric acid addition on disaggregation of crystalline hydroxyapatite nanoparticles under calcium-rich conditions
Materials Letters,156:39-41 2015
Author:Masaki Kakiage, Kenta Iwase, and Hidehiko Kobayashi


Property Development for Biaxial Drawing of Ethylene-Tetrafluoroehtylene Copolymer Films and Resultant Fractural Behavior Analyzed by in Situ X-ray Measurements
The Journal of Physical Chemistry B,119(11):4284-4293 2014
Author:Hiroki Uehara, Yasunori Ono, Masaki Kakiage, Takumi Sakamura, Hiroyasu Masunaga, Yasumasa Yukawa, Yoshiaki Higuchi, Hiroki Kamiya, and Takeshi Yamanobe


Robust and transparent membrane of crystalline silicone via a melt-drawing technique
Journal of Materials Chemistry C,2(2):373-381 2014
Author:Hiroki Uehara, Tomohiro Obana, Masaki Kakiage, Hidekazu Tanaka, Hiroyasu Masunaga, Takeshi Yamanobe, and Eiichi Akiyama


In-situ SAXS Analysis during Uniaxial Drawing of Polyethylene-block-Polystyrene Copolymer Film
Key Engineering Materials,596:50-54 2014
Author:Hiroki Uehara, Masaki Kakiage, Hidekazu Tanaka, and Takeshi Yamanobe


Synthesis of Boron Carbide Powder by Soft Chemical Process
Journal of the Technical Association of Refractories, Japan,33(3):155-167 2013
Author:Masaki Kakiage and Hidehiko Kobayashi


Effect of addition of tartaric acid on synthesis of boron carbide powder from condensed boric acid-glycerin product
Journal of Alloys and Compounds,573:58-64 2013
Author:Naoki Tahara, Masaki Kakiage, Ikuo Yanase, and Hidehiko Kobayashi


Microstructure in precursor formed by controlling composition of condensed boric acid-poly(vinyl alcohol) product for low-temperature synthesis of boron carbide powder
Journal of the Ceramic Society of Japan,121(1):40-44 2013
Author:Masaki Kakiage, Naoki Tahara, Rie Watanabe, Ikuo Yanase, and Hidehiko Kobayashi


Effect of Molecular Structure of Polyols with Different Molecular Characteristics on Synthesis of Boron Carbide Powder
Key Engineering Materials,534:61-65 2013
Author:Masaki Kakiage, Naoki Tahara, Yusuke Tominaga, Satomi Yanagidani, Ikuo Yanase, and Hidehiko Kobayashi


Preparation of Crystalline Turbostratic Boron Nitride Nanoparticles by Combination of Precursor Compound Formation and Impurity Segregation from Boric Acid and Urea
Key Engineering Materials,534:55-60 2013
Author:Masaki Kakiage, Daisuke Yoshikoshi, Ikuo Yanase, and Hidehiko Kobayashi


Phase Transition of Poly(tetramethyl-p-silphenylenesiloxane) As Revealed by in Situ X-ray and NMR Measurements
Macromolecules,45(18):7446-7453 2012
Author:Hiroki Uehara, Tomohiro Obana, Masaki Kakiage, Eiichi Akiyama, and Takeshi Yamanobe


高分子材料の延伸過程におけるin situ NMR測定法の開発と応用
高分子論文集,69(5):235-241 2012
Author:山延健、撹上将規、宮崎紀明、森田翔、上原宏樹


Nanowrinkled and Nanoporous Polyethylene Membranes via Entanglement Arrangement Control
Advanced Functional Materials,22(10):2048-2057 2012
Author:Hiroki Uehara, Takuya Tamura, Masaki Kakiage, and Takeshi Yamanobe


有機化合物を用いた炭化ホウ素粉末の低温合成の現状と今後の動向
Journal of the Society of Inorganic Materials, Japan,19(357):117-125 2012
Author:撹上将規、小林秀彦


Synthesis of boron carbide powder in relation to composition and structural homogeneity of precursor using condensed boric acid-polyol product
Powder Technology,221:257-263 2012
Author:Masaki Kakiage, Yusuke Tominaga, Ikuo Yanase, and Hidehiko Kobayashi


Structural change with blending of crystalline/amorphous block copolymers having different types of microphase separations
Polymer,52(26):6146-6153 2011
Author:Masaki Kakiage, Miho Sekiya, Takeshi Yamanobe, and Hiroki Uehara


ソフト化学プロセスを用いた炭化ほう素粉末の合成
耐火物,63(8):372-384 2011
Author:撹上将規、小林秀彦


Effect of boron oxide/carbon arrangement of precursor derived from condensed polymer-boric acid product on low-temperature synthesis of boron carbide powder
Journal of the Ceramic Society of Japan,119(6):422-425 2011
Author:Masaki Kakiage, Naoki Tahara, Satomi Yanagidani, Ikuo Yanase, and Hidehiko Kobayashi


Low-temperature synthesis of boron carbide powder from condensed boric acid-glycerin product
Materials Letters,65(12):1839-1841 2011
Author:Masaki Kakiage, Naoki Tahara, Ikuo Yanase, and Hidehiko Kobayashi


Nano-Platelet Structure of Clay Materials Observed by Atomic Force Microscope
Key Engineering Materials,459:57-61 2011
Author:Masaki Kakiage, Rie Takamatsu, Hiroki Uehara, Takeshi Yamanobe, and Keizo Suzuki


Structural and property changes during uniaxial drawing of ethylene-tetrafluoroethylene copolymer films as analyzed by in-situ X-ray measurements
Polymer,52(4):1172-1179 2011
Author:Yasunori Ono, Masaki Kakiage, Takeshi Yamanobe, Yasumasa Yukawa, Yoshiaki Higuchi, Hiroki Kamiya, Kiyotaka Arai, and Hiroki Uehara


Effects of Dispersion and Arrangement of Clay on Thermal Diffusivity of Polyimide-Clay Nanocomposite Film
Journal of Applied Polymer Science,119(5):3010-3018 2011
Author:Masaki Kakiage and Shinji Ando


Practical NMR Analysis of Morphology and Structure of Polymers
Annual Reports on NMR Spectroscopy,70:203-239 2010
Author:Takeshi Yamanobe, Hiroki Uehara, and Masaki Kakiage


Hierarchical constraint distribution of ultra-high molecular weight polyethylene fibers with different preparation methods
Journal of Materials Science,45(10):2574-2579 2010
Author:Masaki Kakiage, Takuya Tamura, Syozo Murakami, Hiroshi Takahashi, Takeshi Yamanobe, and Hiroki Uehara


Structure and Property Gradation from Surface to Bulk of Poly(L-lactic acid)/Poly(D-lactic acid) Blended Films as Estimated from Nanoscratch Tests Using Scanning Probe Microscopy
ACS Applied Materials & Interfaces,2(3):633-638 2010
Author:Masaki Kakiage, Tomoyuki Ichikawa, Takeshi Yamanobe, Hiroki Uehara, and Daisuke Sawai


Molecular Aggregation Structures of Polyimide Films at Very High Pressure Analyzed by Synchrotron Wide-Angle X-ray Diffraction
Macromolecules,43(5):2115-2117 2010
Author:Kazuhiro Takizawa, Junji Wakita, Masaki Kakiage, Hiroyasu Masunaga, and Shinji Ando


Novel Design Solving the Conductivity vs Water-Uptake Trade-Off for Polymer Electrolyte Membrane by Bicontinuous Crystalline/Amorphous Morphology of Block Copolymer
Macromolecules,42(20):7627-7630 2009
Author:Hiroki Uehara, Masaki Kakiage, Miho Sekiya, Tsukasa Yamagishi, Takeshi Yamanobe, Katsuhiko Nakajima, Toshio Watanabe, Kumiko Nomura, Kohei Hase, and Masatoshi Matsuda


Size-Selective Diffusion in Nanoporous but Flexible Membranes for Glucose Sensors
ACS Nano,3(4):924-932 2009
Author:Hiroki Uehara, Masaki Kakiage, Miho Sekiya, Daisuke Sakuma, Takeshi Yamanobe, Nao Takano, Antoine Barraud, Eric Meurville, and Peter Ryser


Novel in situ NMR Measurement System for Evaluating Molecular Mobility during Drawing from Highly Entangled Polyethylene Melts
Macromolecular Rapid Communications,29(19):1571-1576 2008
Author:Masaki Kakiage, Hiroki Uehara, and Takeshi Yamanobe


Phase Transitions during Heating of Melt-Drawn Ultrahigh Molecular Weight Polyethylenes Having Different Molecular Characteristics
The Journal of Physical Chemistry B,112(17):5311-5316 2008
Author:Masaki Kakiage, Miho Sekiya, Takeshi Yamanobe, Tadashi Komoto, Sono Sasaki, Syozo Murakami, and Hiroki Uehara


Oriented Crystallization Induced by Uniaxial Drawing from Poly(tetrafluoroethylene) Melt
Macromolecules,40(26):9413-9419 2007
Author:Takashi Morioka, Masaki Kakiage, Takeshi Yamanobe, Tadashi Komoto, Yoshiaki Higuchi, Hiroki Kamiya, Kiyotaka Arai, Syozo Murakami, and Hiroki Uehara


Single-Walled Carbon Nanotube Nucleated Solution-Crystallization of Polyethylene
The Journal of Physical Chemistry C,111(51):18950-18957 2007
Author:Hiroki Uehara, Kaori Kato, Masaki Kakiage, Takeshi Yamanobe, and Tadashi Komoto


ポリエチレン溶融延伸過程における一時通過型結晶化挙動のin-situ計測
放射光,20(6):356-366 2007
Author:撹上将規、上原宏樹


高分子科学とNMR
化学工業,58(11):851-856 2007
Author:山延健、撹上将規、上原宏樹


In situ SAXS analysis of extended-chain crystallization during melt-drawing of ultra-high molecular weight polyethylene
Polymer,48(25):7385-7392 2007
Author:Masaki Kakiage, Miho Sekiya, Takeshi Yamanobe, Tadashi Komoto, Sono Sasaki, Syozo Murakami, and Hiroki Uehara


Nanoperiodic Arrangement of Crystal/Amorphous Phases Induced by Tensile Drawing of Highly Entangled Polyethylene
Macromolecules,40(16):5820-5826 2007
Author:Hiroki Uehara, Kei-ichi Takeuchi, Masaki Kakiage, Takeshi Yamanobe, and Tadashi Komoto


Solid-state characterization of polyethylene reactor powders and their structural changes upon annealing
Polymer,48(15):4547-4557 2007
Author:Hiroki Uehara, Ayako Uehara, Masaki Kakiage, Hiroshi Takahashi, Syozo Murakami, Takeshi Yamanobe, and Tadashi Komoto


Straight-Chain Segment Length Distributions in UHMWPE Reactor Powders of Different Morphological Types
International Journal of Polymer Analysis and Characterization,12(3):221-230 2007
Author:V. Galitsyn, S. Gribanov, M. Kakiage, H. Uehara, Svetlana Khizhnyak, P. Pakhomov, Eleonora Moeller, V. Nikitin, V. Zakharov, and A. Tshmel


Molecular Weight Segregation on Surfaces of Polyethylene Blended Films as Estimated from Nanoscratch Tests Using Scanning Probe Microscopy
Langmuir,23(11):5882-5885 2007
Author:Jun-ichi Suwa, Masaki Kakiage, Takeshi Yamanobe, Tadashi Komoto, and Hiroki Uehara


Continuous Film Processing from Ultrahigh-Molecular-Weight Polyethylene Reactor Powder and Mechanical Property Development by Melt Drawing
Industrial & Engineering Chemistry Research,45(23):7801-7806 2006
Author:Hiroki Uehara, Ryota Yoshida, Masaki Kakiage, Takeshi Yamanobe, and Tadashi Komoto


Transient crystallization during drawing from ultra-high molecular weight polyethylene melts having different entanglement characteristics
Polymer,47(23):8053-8060 2006
Author:Masaki Kakiage, Takeshi Yamanobe, Tadashi Komoto, Syozo Murakami, and Hiroki Uehara


Effects of Molecular Characteristics and Processing Conditions on Melt-Drawing Behavior of Ultrahigh Molecular Weight Polyethylene
Journal of Polymer Science Part B: Polymer Physics,44(17):2455-2467 2006
Author:Masaki Kakiage, Takeshi Yamanobe, Tadashi Komoto, Syozo Murakami, and Hiroki Uehara


Remnant Features in Melt Crystallized Samples of Polyethylenes Originated from Reactor Powders
Journal of Macromolecular Science, Part B: Physics,45(3):407-415 2006
Author:Katherina Tsobkallo, Valeria Vasilieva, Masaki Kakiage, Hiroki Uehara, and Alexandre Tshmel


Phase Development Mechanism during Drawing from Highly Entangled Polyethylene Melts
Macromolecular Rapid Communications,27(12):966-970 2006
Author:Hiroki Uehara, Masaki Kakiage, Takeshi Yamanobe, Tadashi Komoto, and Syozo Murakami


Nanoporous Polyethylene Film Prepared from Bicontinuous Crystalline/Amorphous Structure of Block Copolymer Precursor
Macromolecules,39(12):3971-3974 2006
Author:Hiroki Uehara, Tomoyuki Yoshida, Masaki Kakiage, Takeshi Yamanobe, Tadashi Komoto, Kumiko Nomura, Katsuhiko Nakajima, and Masatoshi Matsuda


Structural Arrangement of Crystalline/Amorphous Phases of Polyethylene-block-Polystyrene Copolymer as Induced by Orientation Techniques
Journal of Polymer Science Part B: Polymer Physics,44(12):1731-1737 2006
Author:Hiroki Uehara, Tomoyuki Yoshida, Masaki Kakiage, Takeshi Yamanobe, and Tadashi Komoto


Surface-Deformation Characteristics of Uniaxially Oriented Poly(ethylene terephthalate) Film as Evaluated from Nanoscratch Tests with Scanning Probe Microscopy
Langmuir,22(11):4985-4991 2006
Author:Hiroki Uehara, Tatsuki Asakawa, Masaki Kakiage, Takeshi Yamanobe, and Tadashi Komoto


その他
ミクロ/マクロ複合ネットワーク構造をもつ前駆体粉末からの六方晶窒化ホウ素粉末の低温合成
公益財団法人日本板硝子材料工学助成会成果報告書 , 35:61-65 2017
Author:撹上将規

研究費
科学研究費補助金(研究代表者)
2016 - 2017 , ホウ酸‐ポリオール縮合物繊維からの組織構造形成がもたらすセラミックス繊維の作製 , 若手研究(B)
2012 - 2013 , 高分子材料の構造制御手法を用いた前駆体構造の最適化による炭化ホウ素粉末の低温合成 , 若手研究(B)
2007 - 2008 , 高分解能分光を用いた高分子融体からの変形過程における構造形成のin-situ計測 , 特別研究員奨励費

奨学寄附金
2014 , ミクロ/マクロ複合ネットワーク構造をもつ前駆体粉末からの六方晶窒化ホウ素粉末の低温合成 , 公益財団法人日本板硝子材料工学助成会 平成26年度(第36回)研究助成
2012 , ソフト化学合成法と反応誘起相分離を利用した高結晶性乱層構造窒化ホウ素粉末の低温合成 , 財団法人日本科学協会 平成24年度笹川科学研究助成

教育活動実績

授業等
高分子・繊維材料
高分子物性Ⅱ(旧カリ)
化学演習Ⅰ
機能高分子学特別講義
生活の中の高分子
基礎化学実験Ⅰ
機能高分子学実験Ⅱ
新入生ゼミナール
ファイバー・機能材料学特論Ⅲ(MC)
化学・材料特別講義(MC)