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巽広輔  タツミ ヒロスケ

教員組織学術研究院(理学系)電話番号0263-37-2507
教育組織理学部 理学科 化学コースFAX番号0263-37-2559
職名准教授メールアドレスtatsumi@shinshu-u.ac.jp
住所〒390-8621 長野県松本市旭3-1-1ホームページURL

プロフィール

兼担研究科・学部
環境・エネルギー材料科学研究所
研究分野
電気分析化学
現在の研究課題
生体関連物質の液液界面イオン移動ボルタンメトリー
キーワード:油水界面
酵素電極を用いるヒロドキシルラジカルの高感度検出
キーワード:ヒドロキシルラジカル , 酵素電極
液状炭素電極を用いるポーラログラフィー
キーワード:ポーラログラフィー , 液状炭素電極
所属学会
所属学会
日本化学会
日本農芸化学会
日本分析化学会
電気化学会
日本ポーラログラフ学会
国際電気化学会

所属学会役職担当
日本ポーラログラフ学会 , 理事
学歴
出身大学院
2001 , 京都大学 , 農学研究科 , 応用生命科学専攻

出身学校・専攻等(大学院を除く)
1996 , 京都大学 , 農学部 , 農芸化学科

取得学位
博士(農学) , 京都大学
受賞学術賞
2011 , 志方メダル
研究職歴等
研究職歴
2008- , 現職
2007-2008 , 同助教
2007-2008 , 福井県立大学 生物資源学部 助教
2001-2007 , 福井県立大学 生物資源学部 助手
2001-2007 , 福井県立大学 生物資源学部 助手

研究活動業績

研究業績(著書・
発表論文等)
著書
ベーシックマスター分析化学
オーム社 2013
Author:蟻川芳子ら


バイオ電気化学の実際―バイオセンサ・バイオ電池の実用展開―
シーエムシー出版 2007
Author:池田篤治ほか


論文
Determination of the real potential of chloride ion in water by using a voltaic cell with a dropping carbon fluid electrode
J. Electroanal. Chem.,797:42-46 2017(May)
Author:K. Sato, H. Tatsumi


炭素滴電極を用いるポーラログラフィー
分析化学,66(1):19-25 2017(Jan.)
Author:巽 広輔


Nearly reversible polarographic waves of ferrocenecarboxylate at dropping carbon fluid electrodes
J. Electroanal. Chem.,779:236-240 2016
Author:H. Tatsumi, N. Seike, K. Kubo


Sensitive electrochemical measurement of hydroxyl radical generation induced by the xanthine-xanthine oxidase system
Anal. Biochem.,467:22-27 2014
Author:H. Tatsumi, Y. Tsuchiya, K. Sakamoto


Development of dropping carbon fluid electrodes for polarography
Electrochim. Acta,135:255-259 2014
Author:H. Tatsumi, S. Tanaka


A pyranose dehydrogenase-based biosensor for kinetic analysis of enzymatic hydrolysis of cellulose by cellulases
Enz. Micorb. Technol.,58-59:68-74 2014
Author:N. Cruys-Bagger, S. F. Badino, R. Tokin, M. Gontsarik, S. Fathalinejad, K. Jensen, M. D. Toscano, T. H. Sørensen, K. Borch, H. Tatsumi, P. Väljamäe, P. Westh


A graphene screen-printed carbon electrode for real-time measurements of unoccupied active sites in a cellulase
Anal. Biochem.,447:162-168 2014
Author:N. Cruys-Bagger, H. Tatsumi, K. Borch, P. Westh


Transient Kinetics and Rate-Limiting Steps for the Processive Cellobiohydrolase Cel7A: Effects of Substrate Structure and Carbohydrate Binding Domain
Biochemistry,52:8938-8948 2013
Author:N. Cruys-Bagger, H. Tatsumi, G. R. Ren, K. Borch, P. Westh


バイオセンサを用いる糖質バイオマス分解過程の解析
Chemical Sensors,29(1):9-14 2013
Author:巽広輔


Kinetic Studies on Enzymatic Hydrolysis of Polysaccharides by Amperometric Biosensors
Rev. Polarogr.,58:75-82 2012
Author:H. Tatsumi


An Amperometric Enzyme Biosensor for Real-Time Measurements of Cellobiohydrolase Activity on Insoluble Cellulose
Biotechnol. Bioeng.,109:3199-3204 2012
Author:N. Cruys-Bagger, G. Ren, H. Tatsumi, M. J. Baumann, N. Spodsberg, H. D. Andersen, L. Gorton, K. Borch, P. Westh


Polarography with a dropping carbon electrode
Electrochem. Commun.,20:160-162 2012
Author:H. Tatsumi, M. Shiba


Pre-steady-state Kinetics for Hydrolysis of Insoluble Cellulose by Cellobiohydrolase Cel7A
J. Biol. Chem.,287:18451-18458 2012
Author:N. Cruys-Bagger, J. Elmerdahl, E. Praestgaard, H. Tatsumi, N. Spodsberg, K. Borch, P. Westh


Origin of Initial Burst in Activity for Trichoderma reesei endo-Glucanases Hydrolyzing Insoluble Cellulose
J. Biol. Chem.,287:1252-1260 2012
Author:L. Murphy, N. Cruys-Bagger, H.D. Damgaard, M.J. Baumann, S.N. Olsen, K. Borch, S.F. Lassen, M. Sweeney, H. Tatsumi, P. Westh


Cyclic Voltammetry of Ion Transfer for Phenylpropanolamine Hydrochloride at Water|Nitrobenzene Interface
J. Chin. Chem. Soc.,59:40-45 2012
Author:Irdhawati, H. Tatsumi, I. Noviandri, Buchari, S. Ibrahim


Sensitive Electrochemical Detection of the Hydroxyl Radical Using Enzyme-catalyzed Redox Cycling
Anal. Sci.,27(11):1065-1067 2011
Author:H. Tatsumi, N. Osaku


Ion transfer voltammetry of tryptamine, serotonin, and tryptophan at the nitrobenzene/water interface
J. Electroanal.Chem.,655(2):180-183 2011
Author:H. Tatsumi, T. Ueda


Thermal Modulation Voltammetry at a 1,2-Dichloroethane/Water Microinterface Using Visible Laser Heating with Optically Absorbing Supporting Electrolyte
Anal. Chem.,82:6717-6720 2010
Author:S. Furuhashi, Y. Terauchi, N. Makita, H. Tatsumi, T. Hinoue


Biosensorer i biomasseforskning
Dansk Kemi,91(3):10-13 2010
Author:N. Cruys-Bagger, H. Tatsumi, K. Borch, P. Westh


Current Generation by Fullerene in the Presence of Tetraphenylborate at a Nitrobenzene|Water Interface under Illumination with a Fluorescent Light
Chem. Lett.,39:1104-1105 2010
Author:S. Furuhashi, H. Tatsumi, T. Kimoto, T. Hinoue


Study of the Decomposition of Free Chlorine with Tertiary Ammonium
Anal. Sci.,26:349-353 2010
Author:H. Katano, K. Uematsu, H. Tatsumi, T. Tsukatani


Discoidin Domain of Chitosanase Is Required for Binding to the Fungal Cell Wall
J.Mol. Microbiol. Biotechnol.,18:14-23 2010
Author:H. Kimoto, M. Akamatsu, Y. Fujii, H. Tatsumi, H. Kusaoke, A. Taketo


Activity Measurement of Chitosanase by an Amperometric Biosensor
Anal. Sci.,25(6):825-827 2009
Author:H. Tatsumi, H. Katano, T. Ikeda, H. Kimoto


Voltammetric Studies on the Mechanism of Electron Transfer Reactions at Liquid|Liquid Interfaces
Rev. Polarogr.,54:89-97 2008
Author:H. Tatsumi


Application of Polyammonium Cations to Enzyme-immobilized Electrode: Application as Enzyme Stabilizer for Bilirubin Oxidase
Anal. Sci.,24:1421-1424 2008
Author:H. Katano, H. Tatsumi, T. Hibi, T. Ikeda, T. Tsukatani


Application of Polyammonium Cations to Enzyme-immobilized Electrode: Voltammetric Behavior of Polycation-hexacyanoferrate Anion Complexes and Applicability as Electron-Transfer Mediator
Anal. Sci.,24:1415-1419 2008
Author:H. Katano, H. Tatsumi, T. Hibi, T. Ikeda, T. Tsukatani


A Bioelectrocatalytic Method for Kinetic Measurement of Thermal Inactivation of a Redox Enzyme, Bilirubin Oxidase
Anal. Sci.,24:237-241 2008
Author:T. Ikeda, H. Tatsumi, H. Katano, M. Wanibuchi, T. Hibi, T. Kajino


Voltammetric study of the interfacial electron transferbetween bis(phthalocyaninato)lutetium in 1,2-dichloroethane and hexacyanoferrate in water
J. Electroanal. Chem.,614:61-66 2008
Author:H. Tatsumi, H. Katano


Theory of ac-voltammetric current of electron transfer reaction at liquid|liquid interface
J. Electroanal. Chem.,615:45-50 2008
Author:H. Tatsumi, H. Katano, M. Senda


Cyclic Voltammetry of the Electron Transfer Reaction between Bis(cyclipentadienyl)iron in 1,2-Dichloroethane and Hexacyanoferrate in Water
Anal. Sci.,23:589-591 2007
Author:H. Tatsumi, H. Katano


Kinetic Analysis of Glucoamylase-Catalyzed Hydrolysis of Starch Granules from Various Botanical Sources
Biosci. Biotechnol. Biochem.,71:945-950 2007
Author:H. Tatsumi, H. Katano, T. Ikeda


Room Temperature Molten Salts Based on Benzyldimethyltetradecylammonium Cation and Bis(2-ethylhexyl)sulfosuccinate and Bis(2-ethylhexyl)phosphate Anions, and Their Applicability as Antimicrobial Agents for Textile Products
Bokin Bobai,35:147-152 2007
Author:H. Katano, M. Akita, H. Tatsumi, T. Tsukatani


Kinetic analysis of enzymatic hydrolysis of crystalline cellulose by cellobiohydrolase using an amperometric biosensor
Anal. Biochem.,357:257-261 2006
Author:H. Tatsumi, H. Katano, T. Ikeda


Voltammetric study of the interfacial electron transfer between bis(cyclopentadienyl)iron in 1,2-dichloroethane and in nitrobenzene and hexacyanoferrate in water
J. Electroanal. Chem.,592:121-125 2006
Author:H. Tatsumi, H. Katano


Ion-Transfer Voltammetry of Polyammonium Antimicrobial Agents across a Phospholipid Monolayer at an Oil / Water Interface
Bokin Bobai,34:195-200 2006
Author:H. Katano, I. Kameoka, Y. Murayama, H. Tatsumi, T. Hibi, T. Ikeda, T. Tsukatani


Theory of normal-pulse voltammetric current of electron transfer reaction at liquid/liquid interface
J. Electroanal. Chem.,590:82-89 2006
Author:H. Tatsumi, H. Katano, M. Senda


Halogen-Free Water-Immiscible Ionic Liquids Based on Tetraoctylammonium Cation and Dodecylsulfate and Dodecylbenzenesulfonate Anions, and Their Application as Chelate Extraction Solvent
Anal. Sci.,22:199-200 2006
Author:T. Tsukatani, H. Katano, H. Tatsumi, M. Deguchi, N. Hirayama


Voltammetric Behavior of the Transfer of Mono- and Polyammonium Ions across a Phospholipid Monolayer at the Nitrobenzene | Water Interface
Anal. Sci.,21:1529-1531 2005
Author:H. Katano, Y. Murayama, H. Tatsumi, T. Hibi, T. Ikeda, I. Kameoka, T. Tsukatani


Kinetics of the Surface Hydrolysis of Raw Starch by Glucoamylase
J. Agric. Food Chem.,53:8123-8127 2005
Author:H. Tatsumi, H. Katano


Electrochemical Study of the Assisted Transfer of Silver Ion by 1,5-Cyclooctadiene at the 1,6-Dichlorohexane | WaterInterface
Anal. Sci.,21:901-905 2005
Author:H. Katano, H. Tatsumi, T. Hibi


Voltammetric study of the interfacial electrontransfer between bis(butylcyclopentadienyl)iron in 1,2-dichloroethane and hexacyanoferrate in water
J. Electroanal. Chem.,577:59-65 2005
Author:H. Tatsumi, H. Katano


Voltammetric Study of the Interfacial Electron Transfer between Bis(cyclopentadienyl)iron in Organic Solvents and Hexacyanoferrate in Water
Anal. Sci.,20:1613-1615 2004
Author:H. Tatsumi, H. Katano


Voltammetric Study of the Transfer of Polyammonium Ions at Nitrobenzene | Water Interface
Anal. Sci.,20:1581-1585 2004
Author:H. Katano, I. Kameoka, Y. Murayama, H. Tatsumi, T. Tsukatani, M. Makino


Kinetic Analysis of Enzymatic Hydrolysis of Raw Starch by Glucoamylase Using an Amperometric Glucose Sensor
Chem. Lett.,33:692-693 2004
Author:H. Tatsumi, H. Katano


Ion-transfer Voltammetry at 1,6-Dichlorohexane | and 1,4-Dichlorobutane | Water Interfaces
Talanta,63:185-193 2004
Author:H. Katano, H. Tatsumi, M. Senda


Voltammetric Study of the Transfer of Fluoride Ion at the Nitrobenzene | Water Interface Assisted by Tetraphenylantimony
Anal. Sci.,20:553-556 2004
Author:H. Katano, Y. Murayama, H. Tatsumi


Voltammetric study of electron transfer across the 1,6-dichlorohexane | water interface with the bis(pentamethylcyclopentadienyl)iron(II/III) redox couple
J. Electroanal. Chem.,563:269-275 2004
Author:H. Tatsumi, H. Katano


Ion-Transfer Voltammetry at a Polarized Room-Temperature Molten Salt | Water Interface
Anal. Sci.,19:651-652 2003
Author:H. Katano, H. Tatsumi


Bioelectrocatalysis-based dihydrogen/dioxygen fuel cell operating at physiological pH
Phys. Chem. Chem. Phys.,3:1331-1335 2001
Author:S. Tsujimura, M. Fujita, H. Tatsumi, K. Kano, T. Ikeda


Bioelectrocatalytic reduction of dioxygen to water at neutral pH using bilirubin oxidase as an enzyme and 2,2’-azinobis(3-ethylbenzothiazoline-6-sulfonate) as an electron transfer mediator
J. Electroanal. Chem.,496:69-75 2001
Author:S. Tsujimura, H. Tatsumi, J. Ogawa, S. Shimizu, K. Kano, T. Ikeda


Approximate and empirical expression of the steady-state catalytic current of mediated bioelectrocatalysis to evaluate enzyme kinetics
J. Electroanal. Chem.,496:37-43 2001
Author:T. Ohgaru, H. Tatsumi, K. Kano, T. Ikeda


Kinetic Analysis of Fast Hydrogenase Reaction of Desulfovibrio vulgaris Cells in the Presence of Exogenous Electron Acceptors
J. Phys. Chem. B,104:12079-12083 2000
Author:H. Tatsumi, K. Kano, T. Ikeda


Kinetics of Respiration Reaction of Thiobacillus ferrooxidans with Several Iron(II) Complexes as Electron Donors
Electrochemistry,68:912-915 2000
Author:H. Tatsumi, K. Kawaguchi, K. Kato, K. Kano, T. Ikeda


Electrochemical activity of an Fe(III)-reducing bacterium, Shewanella putrefaciens IR-1, in the presence of alternative electron acceptors
Biotech. Tech.,13:475-478 1999
Author:B. H. Kim, T. Ikeda, H. S. Park, H. J. Kim, M. S. Hyun, K. Kano, K. Takagi, H. Tatsumi


Electrochemical Study of Reversible Hydrogenase Reaction of Desulfovibrio vulgaris Cells with Methyl Viologen as an Electron Carrier
Anal. Chem.,71:1753-1759 1999
Author:H. Tatsumi, K. Takagi, M. Fujita, K. Kano, T. Ikeda


Mechanistic study of the autoxidation of reduced flavin and quinone compounds
J. Electroanal. Chem.,443:236-242 1998
Author:H. Tatsumi, H. Nakase, K. Kano, T. Ikeda


Mediated catalytic current for the oxidation of ethanol produced by Acetobacter aceti cells suspended in solution
J. Electroanal. Chem.,440:265-269 1997
Author:T. Ikeda, K. Kato, H. Tatsumi, K. Kano


Electrocatalytic properties of Acetobacter aceti cells immobilized on electrodes for the quinone-mediated oxidationof ethanol
J. Electroanal. Chem.,430:197-204 1997
Author:T. Ikeda, K. Kato, M. Maeda, H. Tatsumi, K. Kano, K. Matsushita


Electrochemical Control of Hydrogenase Action of Desulfovibrio vulgaris (Hildenborough)
Chem. Lett.,26:5-6 1997
Author:T. Ikeda, K. Takagi, H. Tatsumi, K. Kano

教育活動実績

授業等
2014 , 前期 , 化学分析学
2014 , 前期 , 分析化学実験
2014 , 前期 , 分析化学演習Ⅱ
2014 , 前期 , 化学実験
2014 , 後期 , 生物化学
2014 , 後期 , 化学計測学

社会活動実績

社会活動等
出前講座
6/20 - 7/25 , 滴定セミナー