菅 博幸 (スガ ヒロユキ)
学術研究院(工学系)
工学部 物質化学科
教授
研究者情報
研究キーワード
- 複素環化合物, 付加環化反応, 分子触媒, 合成化学
経歴
研究活動情報
論文
- Mechanistic Insights into Urea-, Thiourea-, and Isothiourea-Based Bifunctional Tetraarylphosphonium Salt Catalysis for Conversion of Carbon Dioxide to Cyclic Carbonates
Yasunori TODA, Daiki SUENAGA, Ren YAMAGUCHI, Hiroyuki SUGA
Eur. J. Org. Chem., 27(16), e202400137-e202400137, 2024年 - Ring-fused hexahydro-1,2,4,5-tetrazines: synthesis, structure, and mechanistic studies on isolable rotational isomers
Yasunori Toda, Airi Kooguchi, Kimiya Sukegawa, Ayaka Kikuchi, Hiroyuki Suga
Chem. Commun., 59(6), 700-703, 2023年 - Visible-Light-Driven C-H Imidation of Arenes and Heteroarenes by a Phosphonium Ylide Organophotoredox Catalyst: Application to C-H Functionalization of Alkenes
Yasunori Toda, Toya Kobayashi, Fumiya Hirai, Takamichi Yano, Makoto Oikawa, Kimiya Sukegawa, Masahiro Shimizu, Fuyuki Ito, Hiroyuki Suga
J. Org. Chem., 88(13), 9574-9578, 2023年 - 多機能な分子性触媒を志向したホスホニウムイリドの創製
戸田泰徳,菅 博幸
有機合成化学協会誌, 81(4), 333-340, 2023年 - Visible-Light-Driven C–H Imidation of Arenes and Heteroarenes by a Phosphonium Ylide Organophotoredox Catalyst: Application to C–H Functionalization of Alkenes
Yasunori TODA, Toya KOBAYASHI, Fumiya HIRAI, Takamichi YANO, Makoto OIKAWA, Kimiya SUKEGAWA, Masahiro SHIMIZU, Fuyuki ITO, Hiroyuki SUGA
J. Org. Chem., 88(13), 9574-9578, 2023年 - Base-mediated Synthesis of Cyclic Dithiocarbamates from 1-Amino-3-chloropropan-2-ol Derivatives and Carbon Disulfide
Yasunori TODA, Masaya IWASAKI, Hiroyuki SUGA
Org. Biomol. Chem., 21(31), 6293-6297, 2023年 - Development of Phosphonium Ylides as Multifunctional Organocatalysts
Yasunori TODA, Hiroyuki SUGA
J. Synth. Org. Chem. Jpn., 81, 333-340, 2023年 - Asymmetric Cycloadditions of Acyclic Carbonyl Ylides with Aldehydes Catalyzed by a Chiral Binaphthyldiimine-Ni(II) Complex: Enantioselective Synthesis of 1,3-Dioxolanes and Mechanistic Studies by DFT Calculations
Yasunori Toda, Kayo Sato, Kensuke Sato, Kazuma Nagasaki, Hirotaka Nakajima, Ayaka Kikuchi, Kimiya Sukegawa, Hiroyuki Suga
Org. Lett., 24(26), 4739-4744, 2022年 - A phosphonium ylide as a visible light organophotoredox catalyst: A mechanistic study
Yasunori Toda, Katsumi Tanaka, Riki Matsuda, Tomoyuki Sakamoto, Shiho Katsumi, Masahiro Shimizu, Fuyuki Ito, Hiroyuki Suga
Chem. Commun., 57(19), 3591-3594, 2021年 - Enantioselective Protonation of Cyclic Carbonyl Ylides by Chiral Lewis Acid Assisted Alcohols
Yasunori Toda, Takayuki Yoshida, Kaoru Arisue, Kazuaki Fukushima, Hiroyoshi Esaki, Ayaka Kikuchi, Hiroyuki Suga
Chem. Eur. J., 27(41), 10578-10582, 2021年 - Switchable synthesis of cyclic carbamates by carbon dioxide fixation at atmospheric pressure
Yasunori Toda, Minoru Shishido, Tatsuya Aoki, Kimiya Sukegawa, Hiroyuki Suga
ROYAL SOC CHEMISTRY, 57(54), 6672-6675, 2021年 - A phosphonium ylide as a ligand for [3 + 2] coupling reactions of epoxides with heterocumulenes under mild conditions
Yasunori Toda, Kousuke Hashimoto, Yoko Mori, Hiroyuki Suga
J. Org. Chem., 85(16), 10980-10987, 2020年 - Synthesis of 1,2,5-Oxadiazinane Derivatives by Photochemical Cycloaddition of Nitrones with Diaminomethanes
Kennosuke Itoh, Atsushi Takashino, Atsushi Ohtsuka, Mizuki Kobe, Shunsuke Sawamura, Ryo Kato, Shigeto Hirayama, Fumika Karaki, Takaaki Mizuguchi, Noriko Sato, Ken Tokunaga, Yasunori Toda, Hiroyuki Suga, Hitoshi Ishida, Hideaki Fujii
CHEMPHOTOCHEM, 4(6), 388-392, 2020年 - Enantioselective synthesis of 8-azabicyclo[3.2.1]octanes via asymmetric 1,3-dipolar cycloadditions of cyclic azomethine ylides using a dual catalytic system
Hiroyuki SUGA, Masahiro YOSHIWARA, Takaaki YAMAGUCHI, Takashi BANDO, Mizuki TAGUCHI, Ayano INABA, Yuichi GOTO, Ayaka KiKUCHI, Kennosuke ITOH, Yasunori TODA
Chem. Commun., 55(11), 1552-1555, 2019年 - Use of trichloroacetonitrile as a hydrogen chloride generator for ring-opening reactions of aziridines
Yasunori TODA, Riki MATSUDA, Shuto GOMYOU, Hiroyuki SUGA
Org. Biomol. Chem., 17(15), 3825-3829, 2019年 - Novel Asymmetric Photodimerization Reaction of Coumarin Derivatives Bearing a Chiral 2-Oxazolidinone Auxiliary
Kennosuke ITOH, Fumiya ODATE, Takuma KARIKOMI, Keishi OBE, Tsutomu MIYAMORI, Hideaki KAMIYA, Kenji YOZA, Kenichiro NAGAI, Hideaki FUJII, Hiroyuki SUGA, Ken TOKUNAGA
RSC Adv., 9(22), 12365-12369, 2019年 - 4-Hydroxymethyl-substituted oxazolidinone synthesis by tetraarylphosphonium salt-catalyzed reactions of glycidols with isocyanates
Yasunori TODA, Shoya TANAKA, Shuto GOMYOU, Ayaka KIKUCHI, Hiroyuki SUGA
Chem. Commun., 55(41), 5761-5764, 2019年 - Visible-light-triggered Catalytic Halohydrin Synthesis from Epoxides and Trichloroacetonitrile by Copper and Iron Salts
Yasunori Toda, Katsumi Tanaka, Riki Matsuda, Hiroyuki Suga
Chem. Lett., 48(12), 1469-1471, 2019年 - Methoxy Groups Increase Reactivity of Bifunctional Tetraarylphosphonium Salt Catalysts for Carbon Dioxide Fixation: A Mechanistic Study
Yasunori Toda, Yutaka Komiyama, Hiroyoshi Esaki, Kazuaki Fukushima, Hiroyuki Suga
J. Org. Chem., 84(23), 15578-15589, 2019年 - Three-Component Reactions of Diazoesters, Aldehydes, and Imines Using a Dual Catalytic System Consisting of a Rhodium(II) Complex and a Lewis Acid
Yasunori TODA, Wakatake KAKU, Makoto TSURUOKA, Sho SHINOGAKI, Tomoka ABE, Hideaki KAMIYA, Ayaka KIKUCHI, Kennosuke ITOH, Hiroyuki SUGA
Org. Lett., 20(9), 2659-2662, 2018年 - ENANTIOSELECTIVE CYCLOADDITIONS BETWEEN ALIPHATIC NITRILE OXIDES AND 2-HYDROXYSTYRENES CATALYZED BY CHIRAL AMINE-UREA
Yasunori TODA, Masato KOYAMA, Hiroyoshi ESAKI, Kazuaki FUKUSHIMA, Hiroyuki SUGA
Heterocycles, 97(1), 147-150, 2018年 - Lewis Acid Catalysis in Intermolecular [2+2] Photocycloaddition of Coumarin-3-carboxamide Bearing 2-Oxazolidinone Auxiliary with n-Propyl Vinyl Ether and Vinyl Pivalate
Kennosuke ITOH, Junya MATSUURA, Hideaki KAMIYA, Ryuki KUDO, Yuki TAKAHASHI, Yuta HASHIMOTO, Kenji YOZA, Ken TOKUNAGA, Hideaki FUJII, Hiroyuki SUGA
Heterocycles, 97(1), 591-603, 2018年 - A Phosphonium Ylide as an Ionic Nucleophilic Catalyst for Primary Hydroxyl Group Selective Acylation of Diols
Yasunori Toda, Tomoyuki Sakamoto, Yutaka Komiyama, Ayaka Kikuchi, Hiroyuki Suga
ACS Catal., 7(9), 6150-6154, 2017年 - Tetraarylphosphonium Salt-Catalyzed Synthesis of Oxazolidinones from Isocyanates and Epoxides
Yasunori Toda, Shuto Gomyou, Shoya Tanaka, Yutaka Komiyama, Ayaka Kikuchi, Hiroyuki Suga
Org. Lett., 19(21), 5786-5789, 2017年 - Amine‐Urea‐Mediated Asymmetric Cycloadditions between Nitrile Oxides and o‐Hydroxystyrenes by Dual Activation
Hiroyuki Suga, Yohei Hashimoto, Yasunori Toda, Kazuaki Fukushima, Hiroyoshi Esaki, Ayaka Kikuchi
Angew. Chem. Int. Ed., 56(39), 11936-11939, 2017年 - Tetraarylphosphonium Salt-Catalyzed Carbon Dioxide Fixation at Atmospheric Pressure for the Synthesis of Cyclic Carbonates
Yasunori Toda, Yutaka Komiyama, Ayaka Kikuchi, and Hiroyuki Suga
ACS CATALYSIS, 6(10), 6906-6910, 2016年 - Chiral Lewis Acid-Catalyzed Enantioselective Cycloadditions between Indoles and Cyclic Carbonyl Ylides Derived from Diazodiketone or Diazoketoester Derivatives
Hiroyuki SUGA, Yurie SEKIKAWA, Shunta MISAWA, Daito KINUGAWA, Rinnosuke ODA, Kennosuke ITOH, Yasunori TODA, Ryotaro KIYONO
J. Org. Chem., 80(13), 6687-6696, 2015年 - Photochemically-induced C–C Bond Formation between Tertiary Amines and Nitrones
Kennosuke ITOH, Ryo KATO, Daito KINUGAWA, Hideaki KAMIYA, Ryuki KUDO, Masayuki HASEGAWA, Hideaki FUJIIA, Hiroyuki SUGA
Org. Biomol. Chem., 13(33), 8919-8924, 2015年 - Diastereoselective Synthesis of Tetrahydrofurans by Lewis Acid Catalyzed Intermolecular Carbenoid−Carbonyl Reaction−Cycloaddition Sequences: Unusual Diastereoselectivity of Lewis Acid Catalyzed Cycloadditions
Yuta HASHIMOTO, Kennosuke ITOH, Akikazu KAKEHI, Motoo SHIRO, Hiroyuki SUGA
J. Org. Chem., 78(12), 6182-6195, 2013年 - Chiral Lewis Acid Catalyzed Asymmetric Cycloadditions of Carbonyl Ylides Generated from Diazoimide Derivatives and their Synthetic Applications to Indolizidine Alkaloids
Hiroyuki SUGA, Yuta HASHIMOTO, Shingo YASUMURA, Ryota TAKEZAWA
J. Org. Chem., 78(21), 10840-10852, 2013年 - Molecular Recognition of 2-(Arylmethylthio)indolizine Derivatives Through an Intramolecular Aene-(cation) Interaction
Akikazu KAKEHI, Kennosuke ITOH, Hiroyuki SUGA, Nobuhiro YAMAGUCHI, Takashi ABE, Yohei YUDA, Haruka KATSUMATA
Heterocycles, 84(2), 753-764, 2012年 - Novel Rearrangements of a 8aH-Pyrido[1,2-d]thieno[2’,3’-b][1,4]thiazepine Derivative
Akikazu KAKEHI, Kennosuke ITOH, Hiroyuki SUGA, Yuuki OHKUBO, Ayaka KOBAYASHI, Takashi NISHI
Heterocycles, 85(2), 305-312, 2012年 - A New Synthetic Approch to Some Functionalized Cyclo[3.2.2]azine Derivatives
Hideyuki MURANAKA, Akikazu KAKEHI, Hiroyuki SUGA, Kennosuke Itoh
Heterocycles, 82(2), 1251-1266, 2011年 - Unexpected Formation of Thiino[3’,4’:4,5]oxazolo[1,3-b][1,3]oxazepine Derivatives
Akikazu KAKEHI, Kennosuke ITOH, Hiroyuki SUGA, Hirofumi KOBAYASHI, Hideyuki MURANAKA
Heterocycles, 83(3), 1013-1016, 2011年 - Asymmetric Cycloaddition Reactions of Diazoesters with 2-Alkenoic Acid Derivatives Catalyzed by Binaphthyldiimine Ni(II) complexes
Hiroyuki Suga, Yasuhisa Furihata, Atsushi Sakamoto, Kennosuke Itoh, Yukihisa Okumura, Teruko Tsuchida, Akikazu Kakehi, Toshihide Baba
J. Org. Chem., 76(18), 7377–7387, 2011年 - Inverse electron demand asymmetric cycloadditions of cyclic carbonyl ylides catalyzed by chiral Lewis acids-Scope and limitations of diazo and olefinic substrates
Suga, H; Higuchi, S; Ohtsuka, M; Ishimoto, D; Arikawa, T; Hashimoto, Y; Misawa, S; Tsuchida, T; Kakehi, A; Baba, T
Tetrahedron, 66(16), 3070-3089, 2010年04月 - Preparation of new nitrogen-bridged heterocycles. 72. A New Approach to 1-Acyl-3-(substituted methylthio)thieno[3',4':4,5]imidazo[1,5-a]pyridine Derivatives
Akikazu KAKEHI, Hiroyuki SUGA, Yukihisa OKUMURA, Kennosuke ITOH, Kouji KOBAYASHI, Yoshihiro AIKAWA, Kotaro MISAWA
Chem. Pharm. Bull., 58(11), 1502-1510, 2010年 - Asymmetric 1,3-Dipolar Cycloaddition Reactions of Nitrile Oxides Catalyzed by Chiral Binaphthyldiimine-Ni(II) Complexes
Hiroyuki SUGA, Yuki ADACHI, Kouhei FUJIMOTO, Yasuhisa FURIHATA, Teruko TSUCHIDA, Akikazu KAKEHI, Toshihide BABA
J. Org. Chem., 74(3), 1099-1113, 2009年 - Preparation of New Nitrogen-bridged Heterocycles 64. A Smooth Formation of 2,4-Diarylpyrido[2,3-b]indolizine-10-carbonitrile Derivatives
Akikazu KAKEHI, Hiroyuki SUGA, Shuichi SATO
Heterocycles, 77(1), 471-481, 2009年 - First Formation of Thiepino[2,3-b]- and Thiepino[3,2-a]indolizine Derivatives
Hidetoshi ISAWA, Hiroyuki SUGA, Akikazu KAKEHI
Heterocycles, 78(2), 319-324, 2009年 - Preparation of New Nitrogen-bridged Heterocycles 67. Syntheses of ,’-Bis-o-, m-, and p-xylene Derivatives and Their Conformational Structures
Akikazu KAKEHI, Hiroyuki SUGA, Yukihisa OKUMURA, Masatoshi SHINOHARA, Tomonao KAKO, Takeshi SEKIGUCHI, Motoo SHIRO
Chem. Pharm. Bull., 57(12), 1385-1390, 2009年 - Reaction of Potassium Pyrazolo[1,5-a]pyridine-2-thiolates with Electron-poor Alkynes
Hidetoshi ISAWA, Akikazu KAKEHI, Hiroyuki SUGA
Hetreocyclic Commun., 14(3), 141-148, 2008年 - Preparation of New Nitrogen-bridged Heterocycles 63. Unexpected Formation of Thieno[3’,4’:4,5]imidazo[1,2-a]pyridines
Akikazu KAKEHI, Hiroyuki SUGA, Atsushi Izumida, Takashi Abe
Heterocycles, 76(1), 391-399, 2008年 - Highly Enantioselective and Diastereoselective 1,3-Dipolar Cycloaddition Reactions between Azomethine Imines and 3-Acryloyl-2-oxazolidinone Catalyzed by Binaphthyldiimine-Ni(II) Complexes
Hiroyuki SUGA, Akira FUNYU, Akikazu KAKEHI
Org. Lett., 9(1), 97-100, 2007年 - Dipole-LUMO/Dipolarophile-HOMO Controlled Asymmetric Cycloadditions of Carbonyl Ylides Catalyzed by Chiral Lewis Acids
Hiroyuki SUGA, Daisuke ISHIMOTO, Satoshi HIGUCHI, Motoo OHTSUKA
Org. Lett., 9(21), 4359-4362, 2007年 - Preparation of New Nitrogen-bridged Heterocycles 59. Syntheses and Intramolecular Interactions of 3-(Acylmethylthio)- and 3-[(3-Ethoxycarbonyl-2-propenyl)thio]thieno[3,4-b]indolizine Derivatives
Akikazu KAKEHI, Hiroyuki SUGA, Hirohide, ISOGAI
Chem. Pharm. Bull., 55(1), 95-101, 2007年 - Syntheses and Conformational Analyses of Bis(indolizin-1-yl) Disulfides
Akikazu KAKEHI, Hiroyuki SUGA, Hiroko OKUNO, Masaki OKUHARA, Akira OHTA
Chem. Pharm. Bull., 55(10), 1458-1465, 2007年 - First ring contraction-desulfurization of 1-(arylcarbonyl)pyrido[2,1-c]-1,4-thiazines to 1-(arylcarbonyl)indolizines and its application to 3-arylthieno[3,2-a]indolizine synthesis
Akikazu KAKEHI, Hiroyuki SUGA, Yuichi GOTO, Nobuhiro YAMAGUCHI
Heterocycles, 74, 521-532, 2007年 - Preparation of new nitrogen-bridged heterocycles. 53. Syntheses of 3-(benzylthio)thieno[3,4-b]indolizine derivatives and their intramolecular arene-arene interactions
Kakehi, A; Ito, S; Suga, H; Miwa, T; Mori, T; Fujii, T; Tanaka, N; Kobayashi, T
CHEMICAL & PHARMACEUTICAL BULLETIN, 51(1), 75-84, 2003年 - Total Synthesis of (±)-Quinolizidine 217A
William H. PEARSON, Hiroyuki SUGA
J. Org. Chem., 64(19), 7040-7047, 1998年 - Enantioselective Synthesis of cis-2-Oxazoline-4-carboxylates by Lewis Acid Catalyzed Formal [3 + 2] Cycloaddition of 5-Alkoxyoxazoles with Aldehydes
Hiroyuki SUGA, Kosei IKAI, Toshikazu IBATA
Tetrahedron Lett., 39(8), 869-872, 1998年 - Preparation of new nitrogen-bridged heterocycles. 46. Selective formation of 4(1H)-8,8a-dihydro-1,4-thiazino[3,4,5-cd]indolizinone and (E)-3-(1,3-oxathiol-2-ylidene)-2(3H)-indolizinone derivatives
Kakehi, A; Ito, S; Suga, H; Kobayashi, T; Hatanaka, S
CHEMICAL & PHARMACEUTICAL BULLETIN, 46(12), 1866-1871, 1998年 - Regio-Selectivity and Relative Reactivity of Ylide Formation in the Reaction of Ketocarbenoid with Hetero-Cumulenes
Toshikazu IBATA, Motomu HIMORI, Kazuaki FUKUSHIMA, Hiroyuki SUGA, Hirofumi NAKANO
Heterocyclic Commun., 2(1), 87-90, 1996年 - Regio-Control of Formal [3 + 2] Cycloadditions of 5-Alkoxyoxazoles with Diethyl Oxomalonate
Hiroyuki SUGA, Xiaolan SHI, Toshikazu IBATA
Chem. Lett., (9), 1673-1676, 1994年 - Highly Diastereoselective Synthesis of 2-Oxazoline-4-carboxylates by Formal [3 + 2] Cycloadditions of a 5-Alkoxyoxazole with -Alkoxyaldehydes Catalyzed by Tin(IV) Chloride
Hiroyuki SUGA, Hiroki FUJIEDA, Yoshihiro HIROTSU, Toshikazu IBATA
J. Org. Chem., 59(12), 3359-3364, 1994年 - Stereoselective Synthesis of 2-Oxazoline-4-carboxylates through Lewis Acid-Catalyzed Formal [3 + 2] Cycloadditions of 5-Alkoxyoxazoles with Aldehydes
Hiroyuki SUGA, Xiaolan SHI, Toshikazu IBATA
J. Org. Chem., 58(26), 7397-7405, 1993年 - Abnormal Diels-Alder Reaction of 5-Alkoxythiazoles with Highly Reactive Dienophiles; 4-Phenyl-3H-1,2,4-triazole-3,5(4H)-dione, Diethyl Azodicarboxylate, and Diethyl Oxomalonate
Xiaolan SHI, Toshikazu IBATA, Hiroyuki SUGA, Kiyoshi MATSUMOTO
Bull. Chem. Soc. Jpn., 65(12), 3315-3321, 1992年 - Abnormal Diels-Alder Reaction of Oxazoles with 4-Phenyl-3H-1,2,4-triazole-3,5(4H)-dione and Diethyl Azodicarboxylate, and X-Ray Crystal Structure of an Adduct
Toshikazu IBATA, Hiroyuki SUGA, Yasushi ISOGAMI, Hatsue TAMURA, Xiaolan SHI
Bull. Chem. Soc. Jpn., 65(11), 2998-3007, 1992年 - Abnormal Diels-Alder Reaction of 5-Alkoxyoxazoles with Tetracyanoethylene and X-Ray Crystal Structure of an Adduct
Toshikazu IBATA, Yasushi ISOGAMI, Hiroyuki NAKAWA, Hatsue TAMURA, Hiroyuki SUGA, Xiaolan SHI, Hiroki FUJIEDA
Bull. Chem. Soc. Jpn., 65(11), 1771-1778, 1992年 - Reactions of 5-Alkoxyoxazoles with Aldehydes in the Presence of Lewis Acid: Regio- and Stereoselective Formation of 4-Alkoxycarbonyl-2-oxazolines
Hiroyuki SUGA, Xiaolan SHI, Hiroki FUJIEDA, Toshikazu IBATA
Tetrahedron Lett., 32(47), 6911-6914, 1991年 - Reaction of Oxazoles with Nitrosobenzene. A Route to 1,2,4-Oxadiazolines
Hiroyuki SUGA, Toshikazu IBATA
Chem. Lett., (7), 1221-1224, 1991年 - Acid-Catalyzed Transformation of -Hydroxy--oxo Acetals to -Oxo Esters. A Novel Deconjugation of 4-Oxo-2-alkenal Acetals
Shuji KANEMASA, Norihiko NAKAGAWA, Hiroyuki SUGA, Otohiko TSUGE
Bull. Chem. Soc. Jpn., 62(1), 180-184, 1989年 - Synthesis of 4-[(E)-1-Alkenyl]-2-hydroxybutanolides and (Z)-4-Alkylidene-2-butenolides through Cycloadditions Using a Phosphorus-Functionalized Nitrile Oxide
Shuji KANEMASA, Norihiko NAKAGAWA, Hiroyuki SUGA, Otohiko TSUGE
Bull. Chem. Soc. Jpn., 62(1), 171-179, 1989年 - Generation of Sulfur-Functionalized Nitrile Oxide, (Phenylthio)acetonitrile Oxide, and Synthetic Applications
Shuji KANEMASA, Yasumasa NORISUE, Hiroyuki SUGA, Otohiko TSUGE
Bull. Chem. Soc. Jpn., 61(11), 3973-3982, 1988年 - Synthesis of 2-(1-Phosphorylalkyl)- and 2-(1-Alkenyl)furans through Nitrile Oxide Cycloaddition Route
Otohiko TSUGE, Shuji KANEMASA, Hiroyuki SUGA
Bull. Chem. Soc. Jpn., 61(6), 2133-2146, 1988年 - Horner-Emmons Olefination of 4-Hydroxy-2-oxoalkylphosphonates and Related Compounds: Applications to the Syntheses of (±)-Gingerol, (±)-Yashabushiketol, and (±)-Dihydroyashabushiketol
Otohiko TSUGE, Shuji KANEMASA, Norihiko NAKAGAWA, Hiroyuki SUGA
Bull. Chem. Soc. Jpn., 60(11), 4091-4098, 1987年 - Synthesis of (Diethoxyphosphoryl)acetonitrile Oxide and Its Cycloaddition to Olefins. Synthetic Applications to 3,5-Disubstituted 2-Isoxazolines
Otohiko TSUGE, Shuji KANEMASA, Hiroyuki SUGA, Norihiko NAKAGAWA
Bull. Chem. Soc. Jpn., 60(7), 2463-2473, 1987年 - An Entry to 5-(1-Alkenyl)-3(2H)-furanones through Cycloaddition of Phosphorus-Functionalized Nitrile Oxide to Acetylene Alcohols. An Effective Synthesis of Geiparvarin
Otohiko TSUGE, Shuji KANEMASA, Hiroyuki SUGA
Chem. Lett., (2), 323-326, 1987年 - Synthesis of a New Phosphorus-Functionalized Nitrile Oxide, -(Diethylphosphono)acetonitrile Oxide, and Cycloaddition Leading to 3-(Diethylphosphonomethyl)-2-isoxazolines
Otohiko TSUGE, Shuji KANEMASA, Hiroyuki SUGA
Chem. Lett., (2), 183-186, 1986年 - A Novel Ring-Opening Reaction of Aziridine Induced by the Formation of Nitrogen-Substituted Carbanion of Nonstabilized Type
Otohiko TSUGE, Shuji KANEMASA, Hiroyuki SUGA, Koyo MATSUDA
Heterocycles, 22(9), 1955-1958, 1984年 - Inverse-Electron-Demand 1,3-Dipolar Cycloadditions Using Organocatalysts
Hiroyuki SUGA, Yasunori TODA
Heterocycles, 106, 1649-1686
書籍等出版物
- Methods and Applications of Cycloaddition Reactions in Organic Syntheses
Manabu ABE, Haruyasu ASAHARA, Ramil Y. BAIAZITOV, Scott BUR, Pauline CHIU, Steven D. R. CHRISTIE, Hervé CLAVIER, Jun DENG, Scott E. DENMARK, Francesco De SARLO, James DOUGLAS, Xu-Fei FU, Michael HARMATA, Richard P. HSUNG, Kennosuke ITOH, Darin E. JONES, Akio KAMIMURA, Chitoshi KITAMURA, Kensuke KIYOKAWA, Sarah Y. Y. LAM, Fabrizio MACHETTI, Satoshi MINAKATA, Louis C. MORRILL, *Nagatoshi NISHIWAKI, Albert PADWA, Hélène PELLISSIER, Edward RICHMOND, Andrew D. SMITH, Takahiro SOETA, Hiroyuki SUGA, Ryukichi TAKAGI, Kiyosei TAKASU, Youhei TAKEDA, Osamu TAMURA, Yutaka UKAJI, Hidemitsu UNO, Xiao-Na WANG, Hayley T. A. WATSON, Yosuke YAMAOKA, Zhi-Xiang YU, 共著
John Wiley & Sons, 175-204 2014年
担当経験のある科目_授業
共同研究・競争的資金等の研究課題
- 有機分子触媒下での逆電子要請型不斉1,3-双極性付加環化反応-方法論の開拓と確立
科学研究費補助金, 基盤研究(C)
2022年 - 2024年 - 「金属/酸」ハイブリッド触媒系における双極性化合物の立体選択的反応の開発
科学研究費補助金, 基盤研究(C)
2019年 - 2021年 - 計算化学的スクリーニングを利用した有機分子触媒反応の設計および開発
科学研究費補助金, 基盤研究(C)(特設分野)
2017年 - 2019年 - イリド活性化法を基軸とする新規立体選択的分子変換法の開拓と合成化学的応用
科学研究費補助金, 基盤研究(C)
2015年 - 2017年 - 架橋ヘテロ原子化合物の構築を基盤とする革新的アルカロイド不斉合成法の開拓
科学研究費補助金, 基盤研究(C)
2012年 - 2014年 - キラルルイス酸を触媒とする汎用性不斉双極性付加環化の開発と合成化学的応用
科学研究費補助金, 新学術領域研究
2008年 - 2010年 - 架橋酸素多環式化合物の汎用性不斉合成法の開拓と合成化学的応用
科学研究費補助金, 基盤研究(C)
2008年 - 2010年 - キラルテクノロジーを用いる触媒的生理活性複素環の合成
科学研究費補助金, 基盤研究(C)
2005年 - 2006年 - キラルルイス酸触媒を用いるカルボニルイリドの不斉付加環化反応の開発
科学研究費補助金, 基盤研究(C)
2004年 - キラルルイス酸を用いるカルボニルイリドの不斉付加環化反応の開発
科学研究費補助金, 基盤研究(C)(一般)
2003年 - 分子内アセタール誘導体の立体選択的合成とその生理活性に関する研究
受託事業
2002年 - 軸不斉金属触媒存在下でのジアゾカルボニル化合物を用いる不斉反応の開発
科学研究費補助金, 基盤研究(C)
2000年 - 軸不斉金属触媒存在下でのジアゾカルボニル化合物を用いる不斉反応の開発
科学研究費補助金, 基盤研究(C)
1999年 - オキサゾールとアルデヒド類との反応による2-オキサゾリンの不斉合成
科学研究費補助金, 奨励研究(A)
1995年 - オキサゾールおよびチアゾールと電子受容性化合物との反応と合成化学への利用
科学研究費補助金, 奨励研究(A)
1991年 - 複素芳香族化合物をジエン,親双極子とする超高圧下の周辺環状付加反応
科学研究費補助金, 奨励研究(A)
1989年 - 複素環化合物の合成及び合成化学的利用
- 立体選択的反応の開発と合成化学的応用
- 分子触媒を用いる新規エナンチオ選択的反応の開発
- 触媒的不斉1,3-双極性付加環化反応の開発