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SHIMIZU Masahiro

Academic OrganizationAcademic Assembly School of Science and Technology Institute of EngineeringTEL+81-26-269-5627
Education and Research OrganizationFaculty of Engineering Department of Chemistry and Material EngineeringFAX+81-26-269-5627
PositionAssociate ProfessorMail
Address4-17-1, Wakasato, Nagano City 380-8553Web site


Research Field
Development of active material for rechargeable batteries
Control of material structure
Inorganic chemistry
Academic Societies
Academic Societies
The Electrochemical Society of Japan
The chemical society of Japan
The surface finishing society of japan
The Rare Earth Society of Japan
The Electrochemical Society (ECS)

Committee of Academic Societies
2021- , 日本材料科学会先端ウェットプロセス研究会 , 幹事
2018-2019 , 日本分析化学会 , 中部支部 幹事
Academic Background
Graduate School
Tottori University , (Department of Chemistry and Biotechnology , Graduate School of Engineering) , 2016

Doctor of engineering , Tottori University
Research Career
Research Career
2023- , Associate Professor


Books, Articles, etc.
多価カチオンのインターカレーションとその 電池反応への応用可能性(ポストリチウムイオン電池の開発動向と実用化への課題)
月刊 車載テクノロジー,技術情報協会 2022

リチウムを使わない次世代の二次電池:電気化学デバイスにおけるキャリアイオンの多様性, 化学同人:化学(月刊)注目の論文:リチウムを使わない次世代の二次電池:電気化学デバイスにおけるキャリアイオンの多様性
化学同人 2019(Dec.)

第7章 第3節 カーボンナノチューブ複合めっき基板の集電体への応用, カーボンナノチューブの表面処理・分散技術と複合化事例
技術情報協会 2019(Dec.)
Author:清水雅裕,新井 進

第 II 編 第3章 シリコン負極用高比表面積銅系集電体, リチウムイオン二次電池用シリコン系負極材の開発動向
CMC出版 2019(Nov.)
Author:清水雅裕,新井 進

第 II 編 第7章 めっき技術を用いたリチウムイオン電池用CNT/Sn電極の開発, リチウムイオン二次電池用炭素系負極材の開発動向
CMC出版 2019(Sep.)
Author:清水雅裕,新井 進

第10章 第3節 集電体一体型ナトリウムイオン二次電池負極の創製, 次世代電池用電極材料の高エネルギー密度、高出力化-リチウム過剰系正極、三元系正極、シリコン系負極、ポストリチウムイオン電池-
情報技術協会 2017(Nov.)
Author:清水雅裕,新井 進

第V編 第1章 フォトレジストを用いた電気めっき法による微細プロセス最適化技術, 最新フォトレジスト材料開発とプロセス最適化技術セス最適化技術
CMC出版 2017(Sep.)
Author:新井 進,清水雅裕

Lithiation/Delithiation of Silicon Heavily Doped with Boron Synthesized Using the Czochralski Process
Energy Advances,2:813-819 2023
Author:M. Shimizu, K. Kimoto, A. Kikuchi, T. Taishi, S. Arai

Cation-Structure Effects on Zinc Electrodeposition and Crystallographic Orientation in Ionic Liquids
ChemElectroChem,9(10):e202200357 2022
Author:M. Shimizu, Y. Sugiyama, M. Horita, K. Yoshii, S. Arai

Intercalation/deintercalation of solvated Mg2+ into/from graphite interlayers
Physical Chemistry Chemical Physics,(23):16981-16988 2021
Author:M. Shimizu, A. Nakahigashi, S. Arai

Dopant Effect on Lithiation/Delithiation of Highly Crystalline Silicon Synthesized Using the Czochralski Process
ACS Applied Energy Materials,4(8):7922-7929 2021
Author:M. Shimizu, K. Kimoto, T. Kawai, T. Taishi, S. Arai

Superior electrical contact characteristics of Ag/CNT composite films formed in a cyanide-free plating bath and tested against corrosion by H2S gas
Materials Letters,303:130504 2021
Author:S. Arai, T. Kikuhara, M. Shimizu, M. Horita

Fabrication of Roughened Electrodeposited Copper Coating on Steel for Dissimilar Joining of Steel and Thermoplastic Resin
Metals,11(4):591 2021
Author:S. Arai, R. Iwashita, M. Shimizu, J. Inoue, M. Horita, T. Nagaoka, M. Itabashi

A phosphonium ylide as a visible light organophotoredox catalyst
Chemical Communications,57:3591-3594 2021
Author:Y. Toda, K. Tanaka, R. Matsuda, T. Sakamoto, S. Katsumi, M. Shimizu, F. Ito, H. Suga

Ligand Exchange Conduction of Lithium Ion in a Pentaglyme- Lithium Bis(trifluoromethylsulfonyl)amide Super-Concentrated Electrolyte
Journal of The Electrochemical Society,168:016506 2021
Author:A. Kitada, K. Kawata, M. Shimizu, M. Saimura, T. Nagata, M. Katahira, K. Fukami, K. Murase

Electrodeposition of Ag/CNT Composite Films from Iodide Plating Baths
Journal of The Electrochemical Society,167(12):122515 2020
Author:S. Arai, T. Kikuhara, M. Shimizu, M. Horita

Superior Durability of Dissimilar Material Joint between Steel and Thermoplastic Resin with Roughened Electrodeposited Nickel Interlayer
Advanced Engineering Materials,22(12):2000739 2020
Author:S. Arai, R. Sugawara, M. Shimizu, J. Inoue, M. Horita, T. Nagaoka, M. Itabashi

Fabrication of CNT/Cu Composite Yarn via Single-Step Electrodeposition
Journal of The Electrochemical Society,167(10):102509 2020
Author:S. Arai, I. Murakami, M. Shimizu, A. Oshigane

Kinetics Study and Degradation Analysis through Raman Spectroscopy of Graphite as a Negative-Electrode Material for Potassium-Ion Batteries
The Journal of Physical Chemistry C 2020
Author:M. Shimizu, T. Koya, A. Nakahigashi, N. Urakami, T. Yamakami, S. Arai

Piperidinium-based Ionic Liquids as an Electrolyte Solvent for Li-Ion Batteries: Effect of Number and Position of Oxygen Atom in Cation Side Chain on Electrolyte Property
Journal of The Electrochemical Society,167:070516 2020
Author:M. Shimizu, K. Yamaguchi, H. Usui, N. Ieuji, T. Yamashita, T. Komura, Y. Domi, T. Nokami, T. Itoh, H. Sakaguchi

Excellent bonding strength between steel and thermoplastic resin using roughened electrodeposited Ni/CNT composite layer without adhesives
Materials Letters,263:127241 2020
Author:S. Arai, R. Sugawara, M. Shimizu, J. Inoue, M. Horita, T. Nagaoka, M. Itabashi

Multi-layered copper foil reinforced by co-deposition of single-walledcarbon nanotube based on electroplating technique
Materials Letters,261:126993 2020
Author:M. Shimizu, T. Ogasawara, T. Ohnuki, S. Arai

Dispersion of multiwalled carbon nanotubes into a diglyme solution, electrodeposition of aluminum-based composite, and improvement of hardness
Journal of Alloys and Compounds,816:152585 2020
Author:Z. Zhang, A. Kitada, T. Chen, K. Fukami, M. Shimizu, S. Arai, Z. Yao, K. Murase

Electrodeposited Cu/MWCNT composite-film: a potential current collector of silicon-based negative-electrodes for Li-ion batteries
RSC Advances,9:21939–21945 2019
Author:M. Shimizu, T. Ohnuki, T. Ogasawara, T. Banno, S. Arai

Alkyl-Chain-Length Dependence of Quaternary Ammonium Cation on Zn Deposition Morphology in Alkaline-based Electrolytes
Journal of The Electrochemical Society,166(10):A2242–A2244 2019
Author:M. Shimizu, K. Hirahara, Y. Ishida, S. Arai

Morphology control of zinc electrodeposition by surfactant addition for alkaline-based rechargeable batteries
Physical Chemistry Chemical Physics,21:7045–7052 2019
Author:M. Shimizu, K. Hirahara, S. Arai

Effect of Film-Forming Additive in Ionic Liquid Electrolyte on Electrochemical Performance of Si Negative-Electrode for LIBs
Journal of The Electrochemical Society,166(2):A268–A276 2019
Author:K. Yamaguchi, Y. Domi, H. Usui, M. Shimizu, S. Morishita, S. Yodoya, T. Sakata, H. Sakaguchi

Tin Oxides as a Negative Electrode Material for Potassium-Ion Batteries
ACS Applied Energy Materials,1(12):6865–6870 2018
Author:M. Shimizu, R. Yatsuzuka, T Koya, T. Yamakami, S. Arai

Intercalation/De-intercalation Behavior of Li-ion Encapsulated by 12-Crown-4-Ether into Graphite Electrode
Journal of The Electrochemical Society,165(13):A3212–A3214 2018
Author:M. Shimizu, T. Koya, M. Umeki, S. Arai

Electrochemical preparation of free-standing carbon-nanotube/Sn composite paper
Materials Letters,220:182–185 2018
Author:M. Shimizu, S. Shimizu, A. Katada, M. Uejima, S. Arai

Suppressing the effect of lithium dendritic growth by the addition of magnesium bis(trifluoromethanesulfonyl)amide
Physical Chemistry Chemical Physics,20(2):1127–1133 2018
Author:M. Shimizu, M. Umeki, S. Arai

Effects of the ether oxygen atom in alkyl side chains on the physical properties of piperidinium ionic liquids
Faraday Discussions,206:523–534 2018
Author:T. Nokami, T. Yamashita, T. Komura, N. Handa, M. Shimizu, K. Yamaguchi, Y. Domi, H. Usui, H. Sakaguchi, T. Itoh

Design of Roughened Current Collector by Bottom-Up Approach Using Electroplating Technique: Charge–Discharge Performance of Sn Negative-Electrode for Na-Ion Batteries
The Journal of Physical Chemistry C,121(49):27285–27294 2017
Author:M. Shimizu, R. Yatsuzuka, M. Horita, T. Yamamoto, S. Arai

Fabrication of Copper/Single-Walled Carbon Nanotube Composites by Electrodeposition using Free-Standing Nanotube Film
Journal of The Electrochemical Society,164(13):D922–D929 2017
Author:S. Arai, K. Kirihata, M. Shimizu, M. Ueda, A. Katada, M. Uejima

Electrochemical Na-Insertion/Extraction Propertyof Ni-Coated Black Phosphorus Prepared by an Electroless Deposition Method
ACS Omega,2(8):4306–4315 2017
Author:M. Shimizu, Y. Tsushima, S. Arai

Li-insertion/extraction properties of three-dimensional Sn electrode prepared by facile electrodeposition method
Journal of Applied Electrochemistry,47(6):727−734 2017
Author:M. Shimizu, M. Munkhbat, S. Arai

Charge−Discharge Properties of a Sn4P3 Negative Electrode in Ionic Liquid Electrolyte for Na-Ion Batteries
ACS Energy Letters,2(5):1139−1143 2017
Author:H. Usui, Y. Domi, K. Fujiwara, M. Shimizu, T. Yamamoto, T. Nohira, R. Hagiwara, H. Sakaguchi

Micro-Scale Columnar Architecture Composed of Copper Nano Sheets by Electrodeposition Technique
Journal of The Electrochemical Society,164(2):D72−D74 2017
Author:S. Arai, M. Ozawa, M. Shimizu

Influence of the structure of the anion in an ionic liquid electrolyte on the electrochemical performance of a silicon negative electrode for a lithium-ion battery
Journal of Power Sources,338:103−107 2017
Author:K. Yamaguchi, Y. Domi, H. Usui, M. Shimizu, K. Matsumoto, T. Nokami, T. Itoh, H. Sakaguchi

Fabrication of Three-Dimensional (3D) Copper/Carbon Nanotube Composite Film by One-Step Electrodeposition
Journal of The Electrochemical Society,163(14):D774−D779 2016
Author:S. Arai, M. Ozawa, M. Shimizu

Niobium-doped titanium oxide anode and ionic liquid electrolyte for a safe sodium-ion battery
Journal of Power Sources,329:428−431 2016
Author:H. Usui, Y. Domi, M. Shimizu, A. Imoto, K. Yamaguchi, H. Sakaguchi

Effect of Phosphorous-Doping on Electrochemical Performance of Silicon Negative-Electrodes in Lithium-Ion Batteries
ACS Applied Materials & Interfaces,8(11):7125−7132 2016
Author:Y. Domi, H. Usui, M. Shimizu, Y. Kakimoto, and H. Sakaguchi

Functional ionic liquid for enhancement of Li-ion transfer: Effect of cation structure on charge-discharge performance of Li4Ti5O12 electrode
Physical Chemistry Chemical Physics,18:5139−5147 2016
Author:M. Shimizu, H. Usui, H. Sakaguchi

Electrochemical Na-Insertion/Extraction Properties of Phosphorus Electrodes in Ionic Liquid Electrolytes
International Journal of Electrochemical Science,10:10132−10144 2015
Author:M. Shimizu, H. Usui, K. Yamane, T. Sakata, T. Nokami, T. Itoh, H. Sakaguchi

Effect of Film-forming Additive on Electrochemical Performance of Silicon Negative-Electrode in Lithium-Ion Batteries
International Journal of Electrochemical Science,10:9678−9686 2015
Author:Y. Domi, H. Usui, M. Shimizu, K. Miwa, H. Sakaguchi

Electrochemical Na-insertion/extraction properties of Sn-P anodes
Electrochemistry,83(10):810−812 2015
Author:H. Usui, T. Sakata, M. Shimizu, and H. Sakaguchi

Electrochemical behavior of SiO as an anode material for Na-ion battery
Journal of Alloys and Compounds,640:440-443 2015
Author:M. Shimizu, H. Usui, K. Fujiwara, K. Yamane, H. Sakaguchi

Nb-Doped Rutile TiO2: a Potential Anode Material for Na-Ion Battery
ACS Applied Materials & Interfaces,7(12):6567−6573 2015
Author:H. Usui, S. Yoshioka, K. Wasada, M. Shimizu, H. Sakaguchi

Analysis of the Deterioration Mechanism of Si Electrode as a Li-Ion Battery Anode Using Raman Microspectroscopy
The Journal of Physical Chemistry C,119(6):2975−2982 2015
Author:M. Shimizu, H. Usui, T. Suzumura, H. Sakaguchi

Effect of cation structure of ionic liquid on anode properties of Si electrodes for LIB
Journal of The Electrochemical Society,161(12):A1765−A1771 2014
Author:M. Shimizu, H. Usui, K. Matsumoto, T. Nokami, T. Itoh, H. Sakaguchi

Electrochemical Na-insertion/extraction properties of SnO thick-film electrodes prepared by gas-deposition
Journal of Power Sources,248:378−382 2014
Author:M. Shimizu, H. Usui, H. Sakaguchi

TiO2/Si composites synthesized by sol–gel method and their improved electrode performance as Li-ion battery anodes
Electrochimica Acta,111:575−580 2013
Author:H. Usui, K. Wasada, M. Shimizu, H. Sakaguchi

Applicability of ionic liquid electrolytes to LaSi2/Si composite thick-film anodes in Li-ion battery
Journal of Power Sources,235:29−35 2013
Author:H. Usui, M. Shimizu, H. Sakaguchi

Research Grants
Grants‐in‐aid for Scientific Research(Research Representative)
2020 - 2022 , 対極電位から再考するマグネシウム二次電池負極としての黒鉛の可能性 , 基盤研究(B)
2018 - 2019 , 高性能金属空気電池の実現に向けたZnの析出形態制御 , 若手研究
2016 - 2017 , めっき法による三次元多孔質構造を有する集電体一体型ナトリウム二次電池負極の創製 , 研究活動スタート支援
2015 - 2016 , アルカリ金属イオン二次電池負極材料の創製とそれを活かす機能性界面の構築 , 特別研究員奨励費

Grants‐in‐aid for Scientific Research(Researcher)
2022 - 2024 , 非シアン浴を用いたAg-Bi合金/CNT複合めっき膜の創製 , 基盤研究C

Other Research Grants
2018 - 2019 , 高効率小型熱交換器用Niブレージング電解膜の創製(A-STEP機能検証フェーズ 試験研究タイプ 平成30年度第1回公募)/分担

2019 - , 公益財団法人矢崎科学技術振興記念財団 国際交流援助
2019 - , 包摂型多価カチオンを用いた析出形態制御に基づくリチウム金属二次電池の長寿命化(公益財団法人浦上奨学会 研究助成)
2019 - , 亜鉛の析出形態制御に基づく高性能空気電池の開発(公益財団法人八洲環境技術振興財団 研究助成)
2018 - , 金属空気電池の高性能化に向けた亜鉛の析出形態制御(池谷科学技術振興財団)
2018 - , 公益社団法人電気化学会 若手研究者の国際交流支援(平成30年度 前期)
2017 - , 銅/カーボンナノチューブ共析膜の電気化学的創製とリチウムイオン電池への展開(新素材情報財団)
2017 - , カーボンナノチューブ/スズ自立膜複合体の電気化学的創製とリチウムイオン電池への応用(村田学術振興財団)
2017 - , 溶媒和イオンのインターカレーションを積極的に利用した高速充放電可能な多価カチオン電池の創製(本多英五郎研究助成)
2016 - , 無電解めっき法を活用した高容量ナトリウムイオン電池用リン系負極の開発(本多英五郎研究助成)
2016 - , めっき法による三次元多孔質銅集電体の開発とナトリウムイオン電池負極への展開(信州大学工学部若里会)
2014 - , アルカリ金属イオン二次電池負極材料の創製(鳥取大学エンカレッジファンド)
2019 - 2020 , 溶媒和イオンのインターカレーションに基づく多価カチオン電池の創製(公益財団法人TAKEUCHI育英奨学会)